Synthesis, characterization and biological activity of bifunctional ionic liquids based on dodine ion.
antifungal agents
bifunctional salts
ionic liquids
sustainable agriculture
systemic acquired resistance
Journal
Pest management science
ISSN: 1526-4998
Titre abrégé: Pest Manag Sci
Pays: England
ID NLM: 100898744
Informations de publication
Date de publication:
Feb 2022
Feb 2022
Historique:
revised:
06
09
2021
received:
10
06
2021
accepted:
09
09
2021
pubmed:
11
9
2021
medline:
12
1
2022
entrez:
10
9
2021
Statut:
ppublish
Résumé
Development of new plant protection strategies has become an urgent matter in modern agriculture, in view of the evidently proved negative effect of currently used active ingredients of pesticides. In recent years, much effort has been made to eliminate the use of pesticides established to be toxic to pollinators. In this study, we present a group of new bifunctional ionic liquids based on dodine (N-dodecylguanidine) cation whose physical and biological properties have been modified relative to those of the commercially available N-dodecylguanidine acetate. The decreased level of residue of active substances in plant tissues reduces their availability to pollinators, which increases the safety of their use. Moreover, lower environmental impact in combination with high antifungal activity and an additional biological function, that is the systemic acquired resistance induction, are in line with the goals of sustainable agriculture. The presented approach shows the possibility of derivatization of commonly used fungicide into the form of bifunctional salts whose physical and biological properties can be easily modified. The paper reports successful design and synthesis of new sustainable and green chemicals for the modern agriculture, being less toxic to the environment and human health but still effective against pathogens. © 2021 Society of Chemical Industry.
Sections du résumé
BACKGROUND
BACKGROUND
Development of new plant protection strategies has become an urgent matter in modern agriculture, in view of the evidently proved negative effect of currently used active ingredients of pesticides. In recent years, much effort has been made to eliminate the use of pesticides established to be toxic to pollinators.
RESULTS
RESULTS
In this study, we present a group of new bifunctional ionic liquids based on dodine (N-dodecylguanidine) cation whose physical and biological properties have been modified relative to those of the commercially available N-dodecylguanidine acetate. The decreased level of residue of active substances in plant tissues reduces their availability to pollinators, which increases the safety of their use. Moreover, lower environmental impact in combination with high antifungal activity and an additional biological function, that is the systemic acquired resistance induction, are in line with the goals of sustainable agriculture.
CONCLUSION
CONCLUSIONS
The presented approach shows the possibility of derivatization of commonly used fungicide into the form of bifunctional salts whose physical and biological properties can be easily modified. The paper reports successful design and synthesis of new sustainable and green chemicals for the modern agriculture, being less toxic to the environment and human health but still effective against pathogens. © 2021 Society of Chemical Industry.
Substances chimiques
Guanidines
0
Ionic Liquids
0
Pesticides
0
dodine
259C423Y98
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
446-455Subventions
Organisme : Fundacja na rzecz Nauki Polskiej
Organisme : Narodowe Centrum Nauki
Organisme : European Regional Development Fund
Organisme : European Union
Organisme : Foundation for Polish Science
Organisme : National Science Centre
Informations de copyright
© 2021 Society of Chemical Industry.
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