Rare-Earth-Modified Titania Nanoparticles: Molecular Insight into Synthesis and Photochemical Properties.


Journal

Inorganic chemistry
ISSN: 1520-510X
Titre abrégé: Inorg Chem
Pays: United States
ID NLM: 0366543

Informations de publication

Date de publication:
04 Oct 2021
Historique:
pubmed: 14 9 2021
medline: 14 9 2021
entrez: 13 9 2021
Statut: ppublish

Résumé

A molecular precursor approach to titania (anatase) nanopowders modified with different amounts of rare-earth elements (REEs: Eu, Sm, and Y) was developed using the interaction of REE nitrates with titanium alkoxides by a two-step solvothermal-combustion method. The nature of an emerging intermetallic intermediate was revealed unexpectedly for the applied conditions via a single-crystal study of the isolated bimetallic isopropoxide nitrate complex [Ti

Identifiants

pubmed: 34515470
doi: 10.1021/acs.inorgchem.1c02134
pmc: PMC8493554
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

14820-14830

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Auteurs

Fredric G Svensson (FG)

Department of Molecular Sciences, Swedish University of Agricultural Sciences, Box 7015, Uppsala SE-75007, Sweden.

Bogdan Cojocaru (B)

Department of Chemistry, University of Bucharest, B-dul Regina Elisabeta, No. 4-12, Bucharest RO-030018, Romania.

Zhen Qiu (Z)

Department of Materials Science and Engineering, Uppsala University, Box 53, Uppsala SE-75103, Sweden.

Vasile Parvulescu (V)

Department of Chemistry, University of Bucharest, B-dul Regina Elisabeta, No. 4-12, Bucharest RO-030018, Romania.

Tomas Edvinsson (T)

Department of Materials Science and Engineering, Uppsala University, Box 53, Uppsala SE-75103, Sweden.

Gulaim A Seisenbaeva (GA)

Department of Molecular Sciences, Swedish University of Agricultural Sciences, Box 7015, Uppsala SE-75007, Sweden.

Carmen Tiseanu (C)

National Institute for Laser, Plasma and Radiation Physics (NILPR), Bucharest-Magurele RO-76900, Romania.

Vadim G Kessler (VG)

Department of Molecular Sciences, Swedish University of Agricultural Sciences, Box 7015, Uppsala SE-75007, Sweden.

Classifications MeSH