Chlorinated paraffins - A historical consideration including remarks on their complexity.


Journal

Chemosphere
ISSN: 1879-1298
Titre abrégé: Chemosphere
Pays: England
ID NLM: 0320657

Informations de publication

Date de publication:
Jan 2022
Historique:
received: 14 07 2021
revised: 20 08 2021
accepted: 24 08 2021
pubmed: 16 9 2021
medline: 25 11 2021
entrez: 15 9 2021
Statut: ppublish

Résumé

Chlorinated paraffins (CPs) are high production volume chemicals currently produced and used in higher quantities than any other medium-size polyhalogenated compound (class). In addition, the composition of industrial CP mixtures is highly complex and poorly understood. In this article, we searched in the literature for the beginning of the chlorination of alkanes and how this substance class developed from niche applications to unmatched quantities in various industrial applications. Also, an estimation was made on the theoretical variety of chloroparaffins and the possible complexity of industrial CP mixtures. These data may explain why little is known about CPs although the production volume throughout the industrial generation was virtually always higher than the one of PCBs and has continued to increase after the ban of the latter.

Identifiants

pubmed: 34523451
pii: S0045-6535(21)02504-2
doi: 10.1016/j.chemosphere.2021.132032
pii:
doi:

Substances chimiques

Hydrocarbons, Chlorinated 0
Paraffin 8002-74-2
Polychlorinated Biphenyls DFC2HB4I0K

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

132032

Commentaires et corrections

Type : CommentIn

Informations de copyright

Copyright © 2021 Elsevier Ltd. All rights reserved.

Auteurs

Walter Vetter (W)

University of Hohenheim, Institute of Food Chemistry (170b), Garbenstr. 28, 70599, Stuttgart, Germany. Electronic address: walter.vetter@uni-hohenheim.de.

Jannik Sprengel (J)

University of Hohenheim, Institute of Food Chemistry (170b), Garbenstr. 28, 70599, Stuttgart, Germany.

Kerstin Krätschmer (K)

University of Hohenheim, Institute of Food Chemistry (170b), Garbenstr. 28, 70599, Stuttgart, Germany; European Union Reference Laboratory (EURL) for halogenated POPs in Feed and Food, Bissierstraße 5, 79114, Freiburg, Germany.

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Classifications MeSH