Design of Persistent and Stable Porous Radical Polymers by Electronic Isolation Strategy.
electronic isolation strategy
photothermal conversion
porous organic polymers
radicals
water evaporation
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
08 Nov 2021
08 Nov 2021
Historique:
revised:
31
08
2021
received:
22
06
2021
pubmed:
16
9
2021
medline:
16
9
2021
entrez:
15
9
2021
Statut:
ppublish
Résumé
Conjugated organic radical polymers with stable radical features are difficult to design because the π conjugation in the polymer backbones makes the radicals readily delocalize and tend to undergo covalent bonding processes. In this work, we report an electronic isolation strategy to design stable porous radical polymers by homocoupling reaction from a meta-position active monomer. The meta linkage ensures less conjugation in the polymer skeletons, localizes the resonant radicals, and prevents them from recombination. The resulting porous radical polymer exhibits exceptional radical characters with ultralow band gap of 0.68 eV, strong yet extended UV/Vis-NIR absorption up to 1800 nm, and high spin density. The above features make the polymer very promising in the photothermal conversion with record-high photothermal temperature increment of ≈∼240 °C and striking solar-driven water evaporation efficiency of 96.8 %. Our results demonstrate the feasibility of electronic isolation of radicals for producing outstanding photothermal materials.
Identifiants
pubmed: 34523773
doi: 10.1002/anie.202108318
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
24424-24429Subventions
Organisme : national natural science foundation of china
ID : 21975078
Organisme : national natural science foundation of china
ID : 52073089
Organisme : natural science foundation of guangdong province
ID : 2019B030301003
Organisme : guangdong basic and applied basic research foundation
ID : 2021A1515010311
Organisme : higher education discipline innovation project
Organisme : recruitment program of global experts
Organisme : china scholarship council
ID : 202006155049
Organisme : china scholarship council
ID : 202006150059
Organisme : natural science foundation of zhejiang province
ID : LZ20E030001
Informations de copyright
© 2021 Wiley-VCH GmbH.
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