Room temperature spontaneous valley polarization in two-dimensional FeClBr monolayer.

The valley degrees of freedom of Bloch electrons provide a proper platform to realize information storage and processing. Using first principles calculations, we propose that the FeClBr monolayer is a ferromagnetic semiconductor with spontaneous valley polarization owing to the combined effect of magnetic exchange interaction and spin-orbit coupling effect. The FeClBr monolayer shows perpendicular magnetic anisotropy, a high Curie temperature of 651 K and a large valley splitting of 188 meV, which are beneficial for the practical applications in valleytronics. Then, the anomalous valley Hall effect can be realized under an in-plane electrical field due to the valley-contrasting berry curvature. According to the optical selectivity rule, the different valleys at