Template-directed synthesis of zeolitic imidazolate framework-8 derived Zn-Al layered double oxides decorated on the electrochemically anodized nanoporous aluminum substrate for thin film microextraction of chlorophenols followed by determination with high-performance liquid chromatography.

In this work, hierarchical ZIF-8 coated anodized aluminum foil was prepared through in situ template-directed method without addition of any zinc salt. The hierarchical sorbent was synthesized by the formation of the final HZIF-8 on the previously created layered double oxide (LDO) template. The LDO template was created by calcining the firstly in situ prepared desired layered double hydroxide (LDH) precursor coated on the electrochemically anodized porous Al foil in an air atmosphere. The microextraction ability of the extracting device was studied through direct immersion thin film microextraction (DI-TFME). The extracted analytes were quantified by high-performance liquid chromatography equipped by UV detector (HPLC-UV). The present strategy was used for the simultaneous extraction and quantification of four selected chlorophenols (CPs) (as model analyte). The variables of the TFME were optimized using response surface methodology (Plackett-Burman and Box-Behnken design). Under the obtained optimum condition, the prepared film presented acceptable extraction properties including low limits of detection (0.03-0.22 µgL

Informations de copyright

Copyright © 2021 Elsevier B.V. All rights reserved.

Déclaration de conflit d'intérêts

Declaration of Competing Interest There are no conflicts to be declared.