Potassium isotope composition of Mars reveals a mechanism of planetary volatile retention.

K isotope Mars parent body size volatile depletion

Journal

Proceedings of the National Academy of Sciences of the United States of America
ISSN: 1091-6490
Titre abrégé: Proc Natl Acad Sci U S A
Pays: United States
ID NLM: 7505876

Informations de publication

Date de publication:
28 09 2021
Historique:
accepted: 28 07 2021
entrez: 21 9 2021
pubmed: 22 9 2021
medline: 22 9 2021
Statut: ppublish

Résumé

The abundances of water and highly to moderately volatile elements in planets are considered critical to mantle convection, surface evolution processes, and habitability. From the first flyby space probes to the more recent "Perseverance" and "Tianwen-1" missions, "follow the water," and, more broadly, "volatiles," has been one of the key themes of martian exploration. Ratios of volatiles relative to refractory elements (e.g., K/Th, Rb/Sr) are consistent with a higher volatile content for Mars than for Earth, despite the contrasting present-day surface conditions of those bodies. This study presents K isotope data from a spectrum of martian lithologies as an isotopic tracer for comparing the inventories of highly and moderately volatile elements and compounds of planetary bodies. Here, we show that meteorites from Mars have systematically heavier K isotopic compositions than the bulk silicate Earth, implying a greater loss of K from Mars than from Earth. The average "bulk silicate" δ

Identifiants

pubmed: 34544856
pii: 2101155118
doi: 10.1073/pnas.2101155118
pmc: PMC8488668
pii:
doi:

Types de publication

Journal Article Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S.

Langues

eng

Sous-ensembles de citation

IM

Subventions

Organisme : Intramural NASA
ID : 80NSSC19K0932
Pays : United States
Organisme : Intramural NASA
ID : 80NSSC21K0379
Pays : United States

Déclaration de conflit d'intérêts

The authors declare no competing interest.

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Auteurs

Zhen Tian (Z)

Department of Earth and Planetary Sciences, McDonnell Center for the Space Sciences, Washington University in St. Louis, St. Louis, MO 63130; t.zhen@wustl.edu wangkun@wustl.edu.

Tomáš Magna (T)

Section of Isotope Geochemistry and Geochronology, Czech Geological Survey, CZ-118 21 Prague, Czech Republic.

James M D Day (JMD)

Scripps Institution of Oceanography, University of California San Diego, La Jolla, CA 92093.

Klaus Mezger (K)

Institut für Geologie, Universität Bern, 3012 Bern, Switzerland.

Erik E Scherer (EE)

Institut für Mineralogie, Universität Münster, D48149 Münster, Germany.

Katharina Lodders (K)

Department of Earth and Planetary Sciences, McDonnell Center for the Space Sciences, Washington University in St. Louis, St. Louis, MO 63130.

Remco C Hin (RC)

Bristol Isotope Group, School of Earth Sciences, University of Bristol, Bristol BS8 1RJ, United Kingdom.

Piers Koefoed (P)

Department of Earth and Planetary Sciences, McDonnell Center for the Space Sciences, Washington University in St. Louis, St. Louis, MO 63130.

Hannah Bloom (H)

Department of Earth and Planetary Sciences, McDonnell Center for the Space Sciences, Washington University in St. Louis, St. Louis, MO 63130.

Kun Wang (K)

Department of Earth and Planetary Sciences, McDonnell Center for the Space Sciences, Washington University in St. Louis, St. Louis, MO 63130; t.zhen@wustl.edu wangkun@wustl.edu.

Classifications MeSH