Post-Synthesis Functionalization Enables Fine-Tuning the Molecular-Sieving Properties of Zeolites for Light Olefin/Paraffin Separations.
functionalization
light olefins
molecular sieves
separation
zeolites
Journal
Advanced materials (Deerfield Beach, Fla.)
ISSN: 1521-4095
Titre abrégé: Adv Mater
Pays: Germany
ID NLM: 9885358
Informations de publication
Date de publication:
Dec 2021
Dec 2021
Historique:
revised:
11
08
2021
received:
13
07
2021
pubmed:
22
9
2021
medline:
22
9
2021
entrez:
21
9
2021
Statut:
ppublish
Résumé
Zeolite molecular sieves are widely used in gas separation and shape-selective catalysis, but these applications often require discriminating differences as little as 0.1 Å. Molecular sieving with such size selectivity demands zeolites with highly tunable pore diameters and adsorption properties, which are technically challenging to prepare. Nevertheless, it is shown that a wide range of organic functional groups can be covalently functionalized onto the interior pore walls of the zeolites, MOR, LTL, FAU, and MFI, to systematically "tune" their effective pore diameters with respect to the size of organic groups. For organic functionalization, small and aggressive organic electrophiles are used (e.g., organo-halide and -diazonium) as grafting agents, which are accessible to the intracrystalline void space, forming a C-O
Identifiants
pubmed: 34545976
doi: 10.1002/adma.202105398
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2105398Subventions
Organisme : NRF
Organisme : Ministerstvo Školství, Mládeže a Tělovýchovy
ID : CZ.02.1.01/0.0 /0.0/15_003/0000417-CUCAM
Informations de copyright
© 2021 Wiley-VCH GmbH.
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