Multifunctional Deformable Organic Semiconductor Single Crystals.

flexible crystals optical waveguides organic phototransistors organic semiconductors

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
06 Dec 2021
Historique:
revised: 10 09 2021
received: 09 08 2021
pubmed: 28 9 2021
medline: 28 9 2021
entrez: 27 9 2021
Statut: ppublish

Résumé

We report the first organic semiconductor crystal with a unique combination of properties that can be used as a multifunctional optoelectronic device. Mechanically flexible single crystals of 9,10-bis(phenylethynyl)anthracene (BPEA) can function as a phototransistor, photoswitch, and an optical waveguide. The material can exist as two structurally different solid phases, with single crystals of one of the phases being elastic at room temperature while those of the other are brittle and become plastic at higher temperature. The output and transfer characteristics of the devices were characterized by measuring the generation and temporal response of the switching of the photogenerated current. The current-voltage characteristics of both phases exhibit linearity and symmetry about the positive and negative voltages. The crystals transmit light in the telecommunications range with significantly low optical loss for an organic crystalline material.

Identifiants

pubmed: 34570413
doi: 10.1002/anie.202110676
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

26151-26157

Subventions

Organisme : New York University Abu Dhabi

Informations de copyright

© 2021 Wiley-VCH GmbH.

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Auteurs

Durga Prasad Karothu (DP)

Smart Materials Lab, New York University Abu Dhabi, PO Box 129188, Abu Dhabi, UAE.

Ghada Dushaq (G)

Division of Engineering, New York University Abu Dhabi, PO Box 129188, Abu Dhabi, UAE.

Ejaz Ahmed (E)

Smart Materials Lab, New York University Abu Dhabi, PO Box 129188, Abu Dhabi, UAE.

Luca Catalano (L)

Smart Materials Lab, New York University Abu Dhabi, PO Box 129188, Abu Dhabi, UAE.

Mahmoud Rasras (M)

Division of Engineering, New York University Abu Dhabi, PO Box 129188, Abu Dhabi, UAE.

Panče Naumov (P)

Smart Materials Lab, New York University Abu Dhabi, PO Box 129188, Abu Dhabi, UAE.
Molecular Design Institute, Department of Chemistry, New York University, 100 Washington Square East, New York, NY, 10003, USA.

Classifications MeSH