Facile Synthesis of Sulfonyl Chlorides/Bromides from Sulfonyl Hydrazides.
NBS
NCS
sulfonyl bromides
sulfonyl chlorides
sulfonyl hydrazides
Journal
Molecules (Basel, Switzerland)
ISSN: 1420-3049
Titre abrégé: Molecules
Pays: Switzerland
ID NLM: 100964009
Informations de publication
Date de publication:
13 Sep 2021
13 Sep 2021
Historique:
received:
13
08
2021
revised:
10
09
2021
accepted:
10
09
2021
entrez:
28
9
2021
pubmed:
29
9
2021
medline:
29
9
2021
Statut:
epublish
Résumé
A simple and rapid method for efficient synthesis of sulfonyl chlorides/bromides from sulfonyl hydrazide with NXS (X = Cl or Br) and late-stage conversion to several other functional groups was described. A variety of nucleophiles could be engaged in this transformation, thus permitting the synthesis of complex sulfonamides and sulfonates. In most cases, these reactions are highly selective, simple, and clean, affording products at excellent yields.
Identifiants
pubmed: 34577023
pii: molecules26185551
doi: 10.3390/molecules26185551
pmc: PMC8471771
pii:
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Subventions
Organisme : National Natural Science Foundation of China
ID : 21572126
Organisme : National Natural Science Foundation of China
ID : 21801214
Organisme : Natural Science Foundation of Henan
ID : 202300410016
Organisme : the Higher Educa- 180 tion Institution Key Research Project Plan of Henan Province of China
ID : 20B150019
Organisme : the Science and Technology Research Plan Project of Henan Province
ID : 202102210224
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