Noncovalent CH-π and π-π Interactions in Phosphoramidite Palladium(II) Complexes with Strong Conformational Preference.
NMR spectroscopy
conformational analysis
noncovalent interactions
phosphoramidites
supramolecular balance
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
01 12 2021
01 12 2021
Historique:
received:
23
05
2021
pubmed:
30
9
2021
medline:
30
9
2021
entrez:
29
9
2021
Statut:
ppublish
Résumé
The weak noncovalent interactions and flexibility of ligands play a key role in enantioselective metal-catalyzed reactions. In transition metal complexes and their catalytic applications, the experimental assessment and the design of key interactions is as difficult as the prediction of the enantioselectivities, especially for flexible, privileged ligands such as chiral phosphoramidites. Therefore, the interligand interactions in cis-Pd
Identifiants
pubmed: 34585835
doi: 10.1002/anie.202106881
pmc: PMC9298319
doi:
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM
Pagination
25832-25838Subventions
Organisme : Deutsche Forschungsgemeinschaft
ID : SPP 1807 Dispersion
Organisme : H2020 European Research Council
ID : ERC-CoG 614182
Informations de copyright
© 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
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