Hydrophilic-interaction-based magnetically assisted matrix solid-phase dispersion extraction of carbadox and olaquindox in feeds.
attapulgite
carbadox
hydrophilic interaction
magnetically assisted matrix solid-phase dispersion extraction
olaquindox
Journal
Journal of the science of food and agriculture
ISSN: 1097-0010
Titre abrégé: J Sci Food Agric
Pays: England
ID NLM: 0376334
Informations de publication
Date de publication:
30 Mar 2022
30 Mar 2022
Historique:
revised:
03
09
2021
received:
21
07
2021
accepted:
02
10
2021
pubmed:
3
10
2021
medline:
11
3
2022
entrez:
2
10
2021
Statut:
ppublish
Résumé
Carbadox and olaquindox have been banned from feeds since 1998 by the EU because of their mutagenic, photoallergic, and carcinogenic effects. Unfortunately, owing to their outstanding effect, they are frequently abused or misused in animal husbandry. There is an urgent need to develop a sensitive and reliable method for monitoring these drugs in animal feeds. This work reported a new method of hydrophilic-interaction-based magnetically assisted matrix solid-phase dispersion (MMSPD) extraction coupled with reversed-phase liquid chromatography-mass spectrometry for simultaneous determination of carbadox and olaquindox in animal feeds. 3-Trimethoxysilylpropyl methacrylate (γ-MAPS)-modified attapulgite (ATP) was crosslinked with γ-MAPS-modified iron(II,III) oxide (Fe With a simplified procedure and a low amount of sample, the proposed hydrophilic-interaction-based MMSPD method is not only useful for the determination of carbadox and olaquindox in feeds but also holds great promise for the analysis of other polar targets in solid or semisolid matrices. © 2021 Society of Chemical Industry.
Sections du résumé
BACKGROUND
BACKGROUND
Carbadox and olaquindox have been banned from feeds since 1998 by the EU because of their mutagenic, photoallergic, and carcinogenic effects. Unfortunately, owing to their outstanding effect, they are frequently abused or misused in animal husbandry. There is an urgent need to develop a sensitive and reliable method for monitoring these drugs in animal feeds.
RESULTS
RESULTS
This work reported a new method of hydrophilic-interaction-based magnetically assisted matrix solid-phase dispersion (MMSPD) extraction coupled with reversed-phase liquid chromatography-mass spectrometry for simultaneous determination of carbadox and olaquindox in animal feeds. 3-Trimethoxysilylpropyl methacrylate (γ-MAPS)-modified attapulgite (ATP) was crosslinked with γ-MAPS-modified iron(II,III) oxide (Fe
CONCLUSION
CONCLUSIONS
With a simplified procedure and a low amount of sample, the proposed hydrophilic-interaction-based MMSPD method is not only useful for the determination of carbadox and olaquindox in feeds but also holds great promise for the analysis of other polar targets in solid or semisolid matrices. © 2021 Society of Chemical Industry.
Substances chimiques
Quinoxalines
0
olaquindox
G3LAW9U88T
Carbadox
M2X04R2E2Y
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
2080-2089Subventions
Organisme : National Natural Science Foundation of China
ID : 21405085
Organisme : Natural Science Foundation of Ningbo
ID : 202003N4168
Organisme : Zhejiang Province Public Welfare Technology Application Research Project
ID : LGC19B050004
Informations de copyright
© 2021 Society of Chemical Industry.
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