The Oxo-Wall Remains Intact: A Tetrahedrally Distorted Co(IV)-Oxo Complex.
Journal
Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056
Informations de publication
Date de publication:
20 10 2021
20 10 2021
Historique:
pubmed:
6
10
2021
medline:
6
10
2021
entrez:
5
10
2021
Statut:
ppublish
Résumé
In this paper, we report the preparation, spectroscopic and theoretical characterization, and reactivity studies of a Co(IV)-oxo complex bearing an N4-macrocyclic coligand, 12-TBC (12-TBC = 1,4,7,10-tetrabenzyl-1,4,7,10-tetraazacyclododecane). On the basis of the ligand and the structure of the Co(II) precursor, [Co
Identifiants
pubmed: 34609879
doi: 10.1021/jacs.1c04919
doi:
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Research Support, U.S. Gov't, Non-P.H.S.
Langues
eng
Sous-ensembles de citation
IM