A Crystalline Iron Terminal Methylidene.
Journal
Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056
Informations de publication
Date de publication:
20 10 2021
20 10 2021
Historique:
pubmed:
7
10
2021
medline:
7
10
2021
entrez:
6
10
2021
Statut:
ppublish
Résumé
Iron methylidene species are alleged intermediates in the Fischer-Tropsch process and in olefin cyclopropanation, yet iron methylidene complexes with unambiguously established molecular and electronic structures remain elusive. In this study, we characterize an iron terminal methylidene complex by single-crystal X-ray diffractometry (scXRD), CHN combustion elemental analysis,
Identifiants
pubmed: 34613738
doi: 10.1021/jacs.1c08202
doi:
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM