Hybrid light-emitting devices for the straightforward readout of chiral information.
bipolar electrochemistry
chiral recognition
conducting polymers
wireless light emission
Journal
Chirality
ISSN: 1520-636X
Titre abrégé: Chirality
Pays: United States
ID NLM: 8914261
Informations de publication
Date de publication:
12 2021
12 2021
Historique:
revised:
17
09
2021
received:
02
07
2021
accepted:
20
09
2021
pubmed:
8
10
2021
medline:
8
10
2021
entrez:
7
10
2021
Statut:
ppublish
Résumé
Bipolar electrochemistry has gained increasing attention in recent years as an attractive transduction concept in analytical chemistry in general and, more specifically, in the frame of chiral recognition. Herein, we use this concept of wireless electrochemistry, based on the combination of the enantioselective oxidation of a chiral probe with the emission of light from a light-emitting diode (LED), as an alternative for an easy and straightforward readout of the presence of chiral molecules in solution. A hybrid polymer-microelectronic device was designed, using an inherently chiral oligomer, that is, oligo-(3,3'-dibenzothiophene) and a polypyrrole strip as the anode and cathode of a miniaturized LED. The wireless induced redox reactions trigger light emission when the probe with the right chirality is present in solution, whereas no light emission is observed for the opposite enantiomer. The average light intensity shows a linear correlation with the analyte concentration, and the concept opens the possibility to quantify the enantiomeric excess in mixtures of the molecular antipodes.
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM
Pagination
875-882Subventions
Organisme : H2020 European Research Council
ID : 741251
Organisme : H2020 European Research Council (ERC)
Informations de copyright
© 2021 Wiley Periodicals LLC.
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