Thermally Induced Synthesis of Anthracene-, Pyrene- and Naphthalene-Fused Porphyrins.
NIR dyes
anthracene
fused porphyrin
polycyclic aromatic hydrocarbons
thermal cyclodehydrogenation
Journal
ChemistryOpen
ISSN: 2191-1363
Titre abrégé: ChemistryOpen
Pays: Germany
ID NLM: 101594811
Informations de publication
Date de publication:
10 2021
10 2021
Historique:
revised:
07
09
2021
received:
25
08
2021
entrez:
7
10
2021
pubmed:
8
10
2021
medline:
8
10
2021
Statut:
ppublish
Résumé
The synthesis of π-extended porphyrins containing anthracenyl moieties still represents an important challenge. Here, we report on the synthesis of a series of unsubstituted naphthyl-, pyrenyl- and anthracenyl-fused zinc porphyrin derivatives. To this aim, meso-substitued porphyrins are synthesized and the fusion of the PAHs (Polycyclic Aromatic Hydrocarbon) on the β-positions are performed through thermally induced dehydro-aromatization. The fused zinc-porphyrin derivatives are fully characterized and their optical absorption and photoluminescence properties are reported. We also demonstrate that zinc can be removed from the porphyrin core, giving rise to pure C, H, N materials. This work constitutes the first step towards the synthesis of the fully-fused tetra-anthracenylporphyrin.
Identifiants
pubmed: 34617692
doi: 10.1002/open.202100201
pmc: PMC8495684
doi:
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM
Pagination
997-1003Subventions
Organisme : ANR
ID : ANR-16-CE29-0027-01
Organisme : ANR-DFG
ID : ANR-19-CE09-0031-02
Organisme : FLAG-ERA Joint Transnational Call OPERA
ID : FLAG-ERA JTC 2019
Organisme : French National Research Agency
ID : ANR-10-LABX-0035
Informations de copyright
© 2021 The Authors. Published by Wiley-VCH GmbH.
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