Universal Polymeric-to-Colloidal Transition in Melts of Hairy Nanoparticles.

grafted nanoparticles hopping dynamics jamming linear rheology overcrowding parameter soft colloids star polymers

Journal

ACS nano
ISSN: 1936-086X
Titre abrégé: ACS Nano
Pays: United States
ID NLM: 101313589

Informations de publication

Date de publication:
26 Oct 2021
Historique:
pubmed: 9 10 2021
medline: 9 10 2021
entrez: 8 10 2021
Statut: ppublish

Résumé

Two different classes of hairy self-suspended nanoparticles in the melt state, polymer-grafted nanoparticles (GNPs) and star polymers, are shown to display universal dynamic behavior across a broad range of parameter space. Linear viscoelastic measurements on well-characterized silica-poly(methyl acrylate) GNPs with a fixed core radius (

Identifiants

pubmed: 34623796
doi: 10.1021/acsnano.1c06672
pmc: PMC8905532
mid: NIHMS1783062
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

16697-16708

Subventions

Organisme : NHLBI NIH HHS
ID : P01 HL108808
Pays : United States

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Auteurs

Daniele Parisi (D)

Department of Materials Science and Technology and FORTH, Institute of Electronic Structure and Laser, University of Crete, Heraklion 70013, Greece.

Eileen Buenning (E)

Department of Chemical Engineering, Columbia University, New York, New York 10025, United States.

Nikolaos Kalafatakis (N)

Department of Materials Science and Technology and FORTH, Institute of Electronic Structure and Laser, University of Crete, Heraklion 70013, Greece.

Leo Gury (L)

Department of Materials Science and Technology and FORTH, Institute of Electronic Structure and Laser, University of Crete, Heraklion 70013, Greece.
Molecular, Macromolecular Chemistry and Materials, ESPCI Paris, CNRS, PSL Research University, 75005 Paris, France.

Brian C Benicewicz (BC)

Department of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina 29208, United States.

Mario Gauthier (M)

Department of Chemistry, Institute for Polymer Research, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada.

Michel Cloitre (M)

Molecular, Macromolecular Chemistry and Materials, ESPCI Paris, CNRS, PSL Research University, 75005 Paris, France.

Michael Rubinstein (M)

Thomas Lord Departments of Mechanical Engineering and Materials Science, Biomedical Engineering, Chemistry, and Physics, Duke University, Durham, North Carolina 27708, United States.
Institute for Chemical Reaction Design and Discovery (WPI-ICReDD), Hokkaido University, Sapporo 001-0021, Japan.

Sanat K Kumar (SK)

Department of Chemical Engineering, Columbia University, New York, New York 10025, United States.

Dimitris Vlassopoulos (D)

Department of Materials Science and Technology and FORTH, Institute of Electronic Structure and Laser, University of Crete, Heraklion 70013, Greece.

Classifications MeSH