Quantifying Mechanical Properties of Molecular Crystals: A Critical Overview of Experimental Elastic Tensors.

computational chemistry elastic constants elastic tensors mechanical properties molecular crystals

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
01 Feb 2022
Historique:
received: 10 08 2021
pubmed: 20 10 2021
medline: 20 10 2021
entrez: 19 10 2021
Statut: ppublish

Résumé

This review presents a critical and comprehensive overview of current experimental measurements of complete elastic constant tensors for molecular crystals. For a large fraction of these molecular crystals, detailed comparisons are made with elastic tensors obtained using the corrected small basis set Hartree-Fock method S-HF-3c, and these are shown to be competitive with many of those obtained from more sophisticated density functional theory plus dispersion (DFT-D) approaches. These detailed comparisons between S-HF-3c, experimental and DFT-D computed tensors make use of a novel rotation-invariant spherical harmonic description of the Young's modulus, and identify outliers among sets of independent experimental results. The result is a curated database of experimental elastic tensors for molecular crystals, which we hope will stimulate more extensive use of elastic tensor information-experimental and computational-in studies aimed at correlating mechanical properties of molecular crystals with their underlying crystal structure.

Identifiants

pubmed: 34664351
doi: 10.1002/anie.202110716
doi:

Types de publication

Journal Article Review

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202110716

Subventions

Organisme : Australian Research Council
ID : DP130103304
Organisme : Australian Research Council
ID : DP170104816
Organisme : Danmarks Grundforskningsfond
ID : DNRF93

Informations de copyright

© 2021 Wiley-VCH GmbH.

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Auteurs

Peter R Spackman (PR)

School of Molecular Sciences, University of Western Australia, 35 Stirling Highway, Perth, WA, 6009, Australia.
School of Molecular and Life Sciences, Curtin University, Kent Street, Bentley, WA, 6102, Australia.

Arnaud Grosjean (A)

School of Molecular Sciences, University of Western Australia, 35 Stirling Highway, Perth, WA, 6009, Australia.

Sajesh P Thomas (SP)

Department of Chemistry, Aarhus University, Langelandsgade 140, 8000, Århus C, Denmark.
Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi, 110016, India.

Durga Prasad Karothu (DP)

Smart Materials Lab, New York University Abu Dhabi, PO Box 129188, Abu Dhabi, United Arab Emirates.

Panče Naumov (P)

Smart Materials Lab, New York University Abu Dhabi, PO Box 129188, Abu Dhabi, United Arab Emirates.
Molecular Design Institute, Department of Chemistry, New York University, 100 Washington Square East, New York, NY, 10003, USA.

Mark A Spackman (MA)

School of Molecular Sciences, University of Western Australia, 35 Stirling Highway, Perth, WA, 6009, Australia.

Classifications MeSH