Chemometric approaches to resolving base oil mixtures.
Journal
Rapid communications in mass spectrometry : RCM
ISSN: 1097-0231
Titre abrégé: Rapid Commun Mass Spectrom
Pays: England
ID NLM: 8802365
Informations de publication
Date de publication:
15 Jan 2022
15 Jan 2022
Historique:
revised:
15
10
2021
received:
31
07
2021
accepted:
15
10
2021
pubmed:
20
10
2021
medline:
20
10
2021
entrez:
19
10
2021
Statut:
ppublish
Résumé
In the lubrication industry, commercial base oils are commonly made up of blends of base oil stocks from different sources in different ratios to reduce production costs and modulate rheological properties. This practice introduces complexity in lubricant design because as the chemistry of the base oil becomes more complicated, it can become harder to formulate the base oil - particularly when the ratio of the original base oil stocks is unknown. In this study, field ionisation mass spectrometry is used to collect chemical information on a range of base oil mixtures. The resultant data are processed within the Python workspace where molecular formulae are assigned to the components and statistical analyses are performed. A variety of regression techniques including regularised linear models and automated machine learning are evaluated on the data. The use of an automated machine learning pipeline yields insight into effective modelling strategies that could be applied to the data obtained. The best results were obtained using polynomial feature generation combined with ridge cross-validation regression. Overall, with this methodology it is possible to resolve the ratio of group 2 and group 3 base oil within a blended mixture to an accuracy of ±5%. The strategies outlined in this study show how modern data science and chemometrics can be applied successfully to resolve the ratio of a complex mixture.
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e9214Subventions
Organisme : BP Technology Centre
Organisme : Engineering and Physical Sciences Research Council
ID : 1522-0050
Informations de copyright
© 2021 The Authors. Rapid Communications in Mass Spectrometry published by John Wiley & Sons Ltd.
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