Controlled coherent dynamics of [VO(TPP)], a prototype molecular nuclear qudit with an electronic ancilla.
Journal
Chemical science
ISSN: 2041-6520
Titre abrégé: Chem Sci
Pays: England
ID NLM: 101545951
Informations de publication
Date de publication:
22 Sep 2021
22 Sep 2021
Historique:
received:
08
03
2021
accepted:
02
08
2021
entrez:
20
10
2021
pubmed:
21
10
2021
medline:
21
10
2021
Statut:
epublish
Résumé
We show that [VO(TPP)] (vanadyl tetraphenylporphyrinate) is a promising system to implement quantum computation algorithms based on encoding information in multi-level (qudit) units. Indeed, it embeds a nuclear spin 7/2 coupled to an electronic spin 1/2 by hyperfine interaction. This qubit-qudit unit can be exploited to implement quantum error correction and quantum simulation algorithms. Through a combined theoretical and broadband nuclear magnetic resonance study, we demonstrate that the elementary operations of such algorithms can be efficiently implemented on the nuclear spin qudit. Manipulation of the nuclear qudit can be achieved by resonant radio-frequency pulses, thanks to the remarkably long coherence times and the effective quadrupolar coupling induced by the strong hyperfine interaction. This approach may open new perspectives for developing new molecular qubit-qudit systems.
Identifiants
pubmed: 34667570
doi: 10.1039/d1sc01358k
pii: d1sc01358k
pmc: PMC8457369
doi:
Types de publication
Journal Article
Langues
eng
Pagination
12046-12055Informations de copyright
This journal is © The Royal Society of Chemistry.
Déclaration de conflit d'intérêts
There are no conflicts to declare.
Références
Nat Commun. 2017 Feb 20;8:14543
pubmed: 28216631
Inorg Chem. 2018 Jan 16;57(2):731-740
pubmed: 29280628
Chem Soc Rev. 2018 Jan 22;47(2):501-513
pubmed: 29147698
Science. 2020 Aug 28;369(6507):1084-1089
pubmed: 32855334
J Am Chem Soc. 2016 Sep 7;138(35):11234-44
pubmed: 27517709
Angew Chem Int Ed Engl. 2012 Oct 8;51(41):10307-10
pubmed: 22907870
Phys Rev Lett. 2017 Nov 3;119(18):187702
pubmed: 29219608
Chem Sci. 2021 Jun 2;12(26):9104-9113
pubmed: 34276940
Phys Rev Lett. 2009 Feb 27;102(8):087603
pubmed: 19257788
Phys Rev Lett. 2008 Jul 25;101(4):047601
pubmed: 18764365
J Am Chem Soc. 2018 Aug 8;140(31):9814-9818
pubmed: 30040890
Phys Rev Lett. 2011 Sep 9;107(11):117203
pubmed: 22026699
J Am Chem Soc. 2016 Feb 24;138(7):2154-7
pubmed: 26853512
J Phys Chem Lett. 2020 Oct 15;11(20):8610-8615
pubmed: 32936660
Chem Sci. 2018 Jun 15;9(29):6183-6192
pubmed: 30090305
Chem Sci. 2020 Jun 11;11(26):6842-6855
pubmed: 32874524
Nat Commun. 2020 Apr 9;11(1):1751
pubmed: 32273510
Nat Chem. 2019 Apr;11(4):301-309
pubmed: 30903036
Dalton Trans. 2016 Oct 25;45(42):16610-16615
pubmed: 27477766
J Am Chem Soc. 2019 Jul 24;141(29):11339-11352
pubmed: 31287678
Chem Sci. 2021 Mar 17;12(15):5621-5630
pubmed: 34168797
Nano Lett. 2018 Dec 12;18(12):7955-7961
pubmed: 30452271
Nat Commun. 2014 Oct 20;5:5304
pubmed: 25328006
J Am Chem Soc. 2016 Feb 3;138(4):1344-8
pubmed: 26739626
Inorg Chem. 2021 Aug 2;60(15):11273-11286
pubmed: 34264061
Phys Rev Lett. 2012 Mar 9;108(10):107204
pubmed: 22463450
Inorg Chem. 2015 Dec 21;54(24):12027-31
pubmed: 26650962
Phys Chem Chem Phys. 2019 Jun 5;21(22):11676-11688
pubmed: 31134254
J Am Chem Soc. 2017 Mar 29;139(12):4338-4341
pubmed: 28263593
J Am Chem Soc. 2014 May 28;136(21):7623-6
pubmed: 24836983
J Am Chem Soc. 2018 Sep 26;140(38):12090-12101
pubmed: 30145887
Nature. 2017 Sep 13;549(7671):242-246
pubmed: 28905916
ACS Cent Sci. 2015 Dec 23;1(9):488-92
pubmed: 27163013
Nat Commun. 2016 Apr 25;7:11377
pubmed: 27109358
J Am Chem Soc. 2016 Nov 9;138(44):14678-14685
pubmed: 27797487
Sci Rep. 2014 Dec 11;4:7423
pubmed: 25502419
J Am Chem Soc. 2014 Oct 8;136(40):14215-22
pubmed: 25203521
J Phys Chem Lett. 2015 Dec 17;6(24):5062-6
pubmed: 26633293