Substituent Effects Provide Access to Tetrasubstituted Ring-Opening Olefin Metathesis of Bicyclo[4.2.0]oct-6-enes.
Journal
ACS organic & inorganic Au
ISSN: 2694-247X
Titre abrégé: ACS Org Inorg Au
Pays: United States
ID NLM: 9918282981206676
Informations de publication
Date de publication:
06 Oct 2021
06 Oct 2021
Historique:
received:
09
07
2021
entrez:
25
10
2021
pubmed:
26
10
2021
medline:
26
10
2021
Statut:
ppublish
Résumé
Herein, we report the origin of unexpected reactivity of bicyclo[4.2.0]oct-6-ene substrates containing an α,β-unsaturated amide moiety in ruthenium-catalyzed alternating ring-opening metathesis polymerization reactions. Specifically, compared with control substrates bearing an ester, alkyl ketone, nitrile, or tertiary amide substituent, α,β-unsaturated substrates with a weakly acidic proton showed increased rates of ring-opening metathesis mediated by Grubbs-type ruthenium catalysts.
Identifiants
pubmed: 34693402
doi: 10.1021/acsorginorgau.1c00016
pmc: PMC8529632
doi:
Types de publication
Journal Article
Langues
eng
Pagination
29-36Subventions
Organisme : NIGMS NIH HHS
ID : R01 GM097971
Pays : United States
Organisme : NIGMS NIH HHS
ID : R35 GM145247
Pays : United States
Informations de copyright
© 2021 The Authors. Published by American Chemical Society.
Déclaration de conflit d'intérêts
The authors declare no competing financial interest.
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