Rigid Cations Induce Enhancement of Microheterogeneity and Exhibit Anomalous Ion Diffusion in Water-Ethanol Mixtures.
Journal
The journal of physical chemistry. B
ISSN: 1520-5207
Titre abrégé: J Phys Chem B
Pays: United States
ID NLM: 101157530
Informations de publication
Date de publication:
11 11 2021
11 11 2021
Historique:
pubmed:
3
11
2021
medline:
27
1
2022
entrez:
2
11
2021
Statut:
ppublish
Résumé
Because of the amphiphilic nature of ethanol in the aqueous solution, ions cause an interesting microheterogeneity where the water molecules and the hydroxy groups of ethanol preferentially solvate the ions, while the ethyl groups tend to occupy the intervening space. Using computer simulations, we study the dynamics of rigid monovalent cations (Li
Identifiants
pubmed: 34726411
doi: 10.1021/acs.jpcb.1c07698
doi:
Substances chimiques
Cations, Monovalent
0
Solvents
0
Water
059QF0KO0R
Ethanol
3K9958V90M
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM