Clip-off Chemistry: Synthesis by Programmed Disassembly of Reticular Materials.
bond breaking
disassembly
metal-organic frameworks
metal-organic polyhedra
reticular materials
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
21 Jan 2022
21 Jan 2022
Historique:
received:
19
08
2021
pubmed:
6
11
2021
medline:
6
11
2021
entrez:
5
11
2021
Statut:
ppublish
Résumé
Bond breaking is an essential process in chemical transformations and the ability of researchers to strategically dictate which bonds in a given system will be broken translates to greater synthetic control. Here, we report extending the concept of selective bond breaking to reticular materials in a new synthetic approach that we call Clip-off Chemistry. We show that bond-breaking in these structures can be controlled at the molecular level; is periodic, quantitative, and selective; is effective in reactions performed in either solid or liquid phases; and can occur in a single-crystal-to-single-crystal fashion involving the entire bulk precursor sample. We validate Clip-off Chemistry by synthesizing two topologically distinct 3D metal-organic frameworks (MOFs) from two reported 3D MOFs, and a metal-organic macrocycle from metal-organic polyhedra (MOP). Clip-off Chemistry opens the door to the programmed disassembly of reticular materials and thus to the design and synthesis of new molecules and materials.
Identifiants
pubmed: 34739177
doi: 10.1002/anie.202111228
pmc: PMC9299102
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202111228Subventions
Organisme : Ministerio de Economía, Industria y Competitividad, Gobierno de España
ID : RTI2018-095622-B-I00
Organisme : European Union's Horizon 2020
ID : 101019003
Informations de copyright
© 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
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