Inverted and fused expanded heteroporphyrins.

Expanded heteroporphyrins are a class of porphyrin macrocycles containing pyrrole, thiophene, furan, selenophene and other heterocyclic rings that are connected to form an internal ring pathway containing a minimum of 17 atoms and more than 18 delocalized π electrons in their conjugated macrocyclic framework. Considering that expanded heteroporphyrins are large in size, these macrocycles are structurally flexible and prefer to adopt various conformations in which one or more pyrrole(s)/heterocycle(s) tend to be in an inverted conformation and pointed outward from the centre of the macrocyclic core. The inverted expanded heteroporphyrins are divided into two classes as follows: (1)