Reusable Cavitand-Based Electrospun Membranes for the Removal of Polycyclic Aromatic Hydrocarbons from Water.


Journal

Small (Weinheim an der Bergstrasse, Germany)
ISSN: 1613-6829
Titre abrégé: Small
Pays: Germany
ID NLM: 101235338

Informations de publication

Date de publication:
01 2022
Historique:
revised: 13 10 2021
received: 17 08 2021
pubmed: 11 11 2021
medline: 28 1 2022
entrez: 10 11 2021
Statut: ppublish

Résumé

The removal of toxic and carcinogenic polycyclic aromatic hydrocarbons (PAHs) from water is one of the most intractable environmental problems nowadays, because of their resistance to remediation. This work introduces a highly efficient, regenerable membrane for the removal of PAHs from water, featuring excellent filter performance and pH-driven release, thanks to the integration of a cavitand receptor in electrospun polyacrylonitrile (PAN) fibers. The role of the cavitand receptor is to act as molecular gripper for the uptake/release of PAHs. To this purpose, the deep cavity cavitand BenzoQxCav is designed and synthetized and its molecular structure is elucidated via X-Ray diffraction. The removal efficiency of the new adsorbent material toward the 16 priority PAHs is demonstrated via GC-MS analyses at ng L

Identifiants

pubmed: 34755446
doi: 10.1002/smll.202104946
doi:

Substances chimiques

Ethers, Cyclic 0
Polycyclic Aromatic Hydrocarbons 0
Resorcinols 0
Water Pollutants, Chemical 0
cavitand 0
Water 059QF0KO0R

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

e2104946

Informations de copyright

© 2021 The Authors. Small published by Wiley-VCH GmbH.

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Auteurs

Mattia Amorini (M)

Dipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale and INSTM UdR Parma, Università di Parma, Parco Area delle Scienze 17/A, Parma, 43123, Italy.

Nicolò Riboni (N)

Dipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale and INSTM UdR Parma, Università di Parma, Parco Area delle Scienze 17/A, Parma, 43123, Italy.

Lucia Pesenti (L)

Dipartimento di Chimica "G. Ciamician" and INSTM UdR Bologna, Università di Bologna, Via Selmi 2, Bologna, 40126, Italy.

Valentina Antonia Dini (VA)

Dipartimento di Chimica "G. Ciamician" and INSTM UdR Bologna, Università di Bologna, Via Selmi 2, Bologna, 40126, Italy.

Alessandro Pedrini (A)

Dipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale and INSTM UdR Parma, Università di Parma, Parco Area delle Scienze 17/A, Parma, 43123, Italy.

Chiara Massera (C)

Dipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale and INSTM UdR Parma, Università di Parma, Parco Area delle Scienze 17/A, Parma, 43123, Italy.

Chiara Gualandi (C)

Dipartimento di Chimica "G. Ciamician" and INSTM UdR Bologna, Università di Bologna, Via Selmi 2, Bologna, 40126, Italy.

Federica Bianchi (F)

Dipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale and INSTM UdR Parma, Università di Parma, Parco Area delle Scienze 17/A, Parma, 43123, Italy.

Roberta Pinalli (R)

Dipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale and INSTM UdR Parma, Università di Parma, Parco Area delle Scienze 17/A, Parma, 43123, Italy.

Enrico Dalcanale (E)

Dipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale and INSTM UdR Parma, Università di Parma, Parco Area delle Scienze 17/A, Parma, 43123, Italy.

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