Unravelling of a [High Spin-Low Spin] ↔ [Low Spin-High Spin] Equilibrium in Spin-Crossover Iron(II) Dinuclear Helicates Using Paramagnetic NMR Spectroscopy.

broken symmetry helicates paramagnetic NMR spin crossover

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
17 Jan 2022
Historique:
revised: 10 11 2021
received: 02 08 2021
pubmed: 11 11 2021
medline: 11 11 2021
entrez: 10 11 2021
Statut: ppublish

Résumé

Spin-crossover between high-spin (HS) and low-spin (LS) states of selected transition metal ions in polynuclear and polymeric compounds is behind their use as multistep switchable materials in breakthrough electronic and spintronic devices. We report the first successful attempt to observe the dynamics of a rarely found broken-symmetry spin state in binuclear complexes, which mixes the states [HS-LS] and [LS-HS] on a millisecond timescale. The slow exchange between these two states, which was identified by paramagnetic NMR spectroscopy in solutions of two spin-crossover iron(II) binuclear helicates that are amenable to molecular design, opens a path to double quantum dot cellular automata for information storage and processing.

Identifiants

pubmed: 34757659
doi: 10.1002/anie.202110310
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202110310

Subventions

Organisme : Spanish MICINN
ID : PGC2018-098630-B-I00
Organisme : Generalitat de Catalunya
ID : ICREA Academia 2018
Organisme : russian science foundation
ID : 17-13-01456

Informations de copyright

© 2021 Wiley-VCH GmbH.

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Auteurs

Dmitry Yu Aleshin (DY)

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova str. 28, 11999, Moscow, Russia.

Rosa Diego (R)

Department de Quimica Inorganica and IN2UB, Universitat de Barcelona, Diagonal 647, 08028, Barcelona, Spain.

Leoní A Barrios (LA)

Department de Quimica Inorganica and IN2UB, Universitat de Barcelona, Diagonal 647, 08028, Barcelona, Spain.

Yulia V Nelyubina (YV)

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova str. 28, 11999, Moscow, Russia.
Moscow Institute of Physics and Technology, Institutskiy per. 9, 141700 Dolgoprudny, Moscow region, Russia.

Guillem Aromí (G)

Department de Quimica Inorganica and IN2UB, Universitat de Barcelona, Diagonal 647, 08028, Barcelona, Spain.

Valentin V Novikov (VV)

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova str. 28, 11999, Moscow, Russia.
Moscow Institute of Physics and Technology, Institutskiy per. 9, 141700 Dolgoprudny, Moscow region, Russia.

Classifications MeSH