Fluids as primary carriers of sulphur and copper in magmatic assimilation.


Journal

Nature communications
ISSN: 2041-1723
Titre abrégé: Nat Commun
Pays: England
ID NLM: 101528555

Informations de publication

Date de publication:
16 Nov 2021
Historique:
received: 11 02 2020
accepted: 22 10 2021
entrez: 17 11 2021
pubmed: 18 11 2021
medline: 18 11 2021
Statut: epublish

Résumé

Magmas readily react with their wall-rocks forming metamorphic contact aureoles. Sulphur and possibly metal mobilization within these contact aureoles is essential in the formation of economic magmatic sulphide deposits. We performed heating and partial melting experiments on a black shale sample from the Paleoproterozoic Virginia Formation, which is the main source of sulphur for the world-class Cu-Ni sulphide deposits of the 1.1 Ga Duluth Complex, Minnesota. These experiments show that an autochthonous devolatilization fluid effectively mobilizes carbon, sulphur, and copper in the black shale within subsolidus conditions (≤ 700 °C). Further mobilization occurs when the black shale melts and droplets of Cu-rich sulphide melt and pyrrhotite form at ∼1000 °C. The sulphide droplets attach to bubbles of devolatilization fluid, which promotes buoyancy-driven transportation in silicate melt. Our study shows that devolatilization fluids can supply large proportions of sulphur and copper in mafic-ultramafic layered intrusion-hosted Cu-Ni sulphide deposits.

Identifiants

pubmed: 34785681
doi: 10.1038/s41467-021-26969-3
pii: 10.1038/s41467-021-26969-3
pmc: PMC8595724
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

6609

Subventions

Organisme : Academy of Finland (Suomen Akatemia)
ID : 306962
Organisme : Academy of Finland (Suomen Akatemia)
ID : 327358
Organisme : Academy of Finland (Suomen Akatemia)
ID : 295129
Organisme : Academy of Finland (Suomen Akatemia)
ID : 306962

Informations de copyright

© 2021. The Author(s).

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Auteurs

Ville J Virtanen (VJ)

Department of Geoscience and Geography, University of Helsinki, Gustaf Hällströminkatu 2, 00014, Helsinki, Finland. ville.z.virtanen@helsinki.fi.

Jussi S Heinonen (JS)

Department of Geoscience and Geography, University of Helsinki, Gustaf Hällströminkatu 2, 00014, Helsinki, Finland.

Ferenc Molnár (F)

Geological Survey of Finland, Vuorimiehentie 5, 02151, Espoo, Finland.
Department of Mineralogy, Institute of Geography and Earth Sciences, Eötvös Loránd University, Pázmány Péter s. 1/C, 1117, Budapest, Hungary.

Max W Schmidt (MW)

Institute of Geochemistry and Petrology, ETH Zürich, Clausiusstrasse 25, 8092, Zürich, Switzerland.

Felix Marxer (F)

Institute of Geochemistry and Petrology, ETH Zürich, Clausiusstrasse 25, 8092, Zürich, Switzerland.
Institute of Mineralogy, Leibniz University Hannover, Callinstraße 3, 30167, Hannover, Germany.

Pietari Skyttä (P)

Department of Geography and Geology, University of Turku, Akatemiankatu 1, FI-20500, Turku, Finland.

Nico Kueter (N)

Earth and Planets Laboratory, Carnegie Institution for Science, 5241 Broad Branch Road, NW, Washington, DC, 20015-1305, USA.

Karina Moslova (K)

Department of Chemistry, University of Helsinki, A.I. Virtasen aukio 1, 00014, Helsinki, Finland.

Classifications MeSH