Enzymatic synthesis and formation kinetics of mono- and di-hydroxylated chlorinated paraffins with the bacterial dehalogenase LinB from Sphingobium indicum.
Dihydroxylated chloroparaffins (CP-diols)
Enzymatic dehalohydroxylation
Hydroxylated chloroparaffins (CP-ols)
In-vitro CP transformation
Persistent organic pollutants (POPs)
Journal
Chemosphere
ISSN: 1879-1298
Titre abrégé: Chemosphere
Pays: England
ID NLM: 0320657
Informations de publication
Date de publication:
Mar 2022
Mar 2022
Historique:
received:
27
06
2021
revised:
11
11
2021
accepted:
14
11
2021
pubmed:
21
11
2021
medline:
27
1
2022
entrez:
20
11
2021
Statut:
ppublish
Résumé
Transformation studies of chlorinated paraffins (CPs) and the effects of CP transformation products on humans, biota and environment are rare. The focus here is on hydroxylation reactions. As for polyhalogenated persistent organic pollutants (POPs) in general, hydroxylation reactions convert lipophilic material to more polar compounds with increased mobility. We investigated the in-vitro transformation of single-chain CP-mixtures to hydroxylated products with the dehalogenase LinB from Sphingobium indicum. C
Identifiants
pubmed: 34800506
pii: S0045-6535(21)03411-1
doi: 10.1016/j.chemosphere.2021.132939
pii:
doi:
Substances chimiques
Hydrocarbons, Chlorinated
0
Paraffin
8002-74-2
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
132939Informations de copyright
Copyright © 2021 The Authors. Published by Elsevier Ltd.. All rights reserved.