Complexation of Np(V) with the Dicarboxylates, Malonate, and Succinate: Complex Stoichiometry, Thermodynamic Data, and Structural Information.
Journal
Inorganic chemistry
ISSN: 1520-510X
Titre abrégé: Inorg Chem
Pays: United States
ID NLM: 0366543
Informations de publication
Date de publication:
20 Dec 2021
20 Dec 2021
Historique:
pubmed:
26
11
2021
medline:
26
11
2021
entrez:
25
11
2021
Statut:
ppublish
Résumé
The complexation of Np(V) with malonate and succinate is studied by different spectroscopic techniques, namely, attenuated total reflection Fourier transform infrared (ATR FT-IR) and extended X-ray absorption fine-structure (EXAFS) spectroscopy, as well as by quantum chemistry to determine the speciation, thermodynamic data, and structural information of the formed complexes. For complex stoichiometries and the thermodynamic functions (log β
Identifiants
pubmed: 34821502
doi: 10.1021/acs.inorgchem.1c01966
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM