Global Analysis of the Mechanical Properties of Organic Crystals.
mechanical properties
nanoindentation
organic crystals
soft materials
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
01 Mar 2022
01 Mar 2022
Historique:
received:
21
10
2021
pubmed:
1
12
2021
medline:
1
12
2021
entrez:
30
11
2021
Statut:
ppublish
Résumé
Organic crystals, although widely studied, have not been considered nascent candidate materials in engineering design. Here we summarize the mechanical properties of organic crystals that have been reported over the past three decades, and we establish a global mechanical property profile that can be used to predict and identify mechanically robust organic crystals. Being composed of light elements, organic crystals populate a narrow region in the mechanical property-density space between soft, disordered organic materials and stiff, ordered materials. Two subsets of extraordinarily stiff and hard organic crystalline materials were identified and rationalized by the normalized number density, strength, and directionality of their intermolecular interactions. We conclude that future lightweight, soft, all-organic components in devices should capitalize on the greatest asset of organic single crystals-namely, the combination of long-range structural order and softness.
Identifiants
pubmed: 34845806
doi: 10.1002/anie.202113988
doi:
Types de publication
Journal Article
Review
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202113988Subventions
Organisme : New York University Abu Dhabi
Informations de copyright
© 2021 Wiley-VCH GmbH.
Références
S. Coyle, C. Majidi, P. LeDuc, K. J. Hsia, Extreme Mech. Lett. 2018, 22, 51-59.
A. Miriyev, K. Stack, H. Lipson, Nat. Commun. 2017, 8, 596.
Y. Wang, S. E. Naleway, B. Wang, Bioact. Mater. 2020, 5, 745-757.
C. Wang, C. C. Sun, CrystEngComm 2020, 22, 1149-1153.
C. M. Reddy, G. R. Krishna, S. Ghosh, CrystEngComm 2010, 12, 2296-2314.
S. Varughese, M. S. R. N. Kiran, U. Ramamurty, G. R. Desiraju, Angew. Chem. Int. Ed. 2013, 52, 2701-2712;
Angew. Chem. 2013, 125, 2765-2777.
A. Mondal, B. Bhattacharya, S. Das, S. Bhunia, R. Chowdhury, S. Dey, C. M. Reddy, Angew. Chem. Int. Ed. 2020, 59, 10971-10980;
Angew. Chem. 2020, 132, 11064-11073.
G. R. Krishna, R. Devarapalli, G. Lal, C. M. Reddy, J. Am. Chem. Soc. 2016, 138, 13561-13567.
P. Commins, D. P. Karothu, P. Naumov, Angew. Chem. Int. Ed. 2019, 58, 10052-10060;
Angew. Chem. 2019, 131, 10154-10163.
P. Xie, R. Zhang, J. Mater. Chem. 2005, 15, 2529-2550.
C. P. Ambulo, S. Tasmim, S. Wang, M. K. Abdelrahman, P. E. Zimmern, T. H. Ware, J. Appl. Phys. 2020, 128, 140901.
H. Yu, T. Ikeda, Adv. Mater. 2011, 23, 2149-2180.
P. Naumov, S. Chizhik, M. K. Panda, N. K. Nath, E. Boldyreva, Chem. Rev. 2015, 115, 12440-12490.
P. Naumov, D. P. Karothu, E. Ahmed, L. Catalano, P. Commins, J. >Mahmoud Halabi, M. B. Al-Handawi, L. Li, J. Am. Chem. Soc. 2020, 142, 13256-13272.
E. Ahmed, D. P. Karothu, P. Naumov, Angew. Chem. Int. Ed. 2018, 57, 8837-8846;
Angew. Chem. 2018, 130, 8974-8984.
M. K. Panda, S. Ghosh, N. Yasuda, T. Moriwaki, G. D. Mukherjee, C. M. Reddy, P. Naumov, Nat. Chem. 2015, 7, 65-72.
A. Worthy, A. Grosjean, M. C. Pfrunder, Y. Xu, C. Yan, G. Edwards, J. K. Clegg, J. C. McMurtrie, Nat. Chem. 2018, 10, 65-69.
L. Zhang, J. B. Bailey, R. H. Subramanian, A. Groisman, A. F. Tezcan, Nature 2018, 557, 86-91.
P. Commins, H. Hara, P. Naumov, Angew. Chem. Int. Ed. 2016, 55, 13028-13032;
Angew. Chem. 2016, 128, 13222-13226.
P. Commins, M. Al-Handawi, D. P. Karothu, G. Raj, P. Naumov, Chem. Sci. 2020, 11, 2606-2613.
D. P. Karothu, J. Weston, I. T. Desta, P. Naumov, J. Am. Chem. Soc. 2016, 138, 13298-13306.
E. Ahmed, D. P. Karothu, M. Warren, P. Naumov, Nat. Commun. 2019, 10, 3723.
S. Takamizawa, in Mechanically responsive materials for soft robotics (Ed.: H. Koshima), Wiley-VCH, Weinheim, 2020, pp. 139-175.
G. Alici, MRS Adv. 2018, 3, 1557-1568.
T. Kim, L. Zhu, R. O. Al-Kaysi, C. J. Bardeen, ChemPhysChem 2014, 15, 400-414.
S. K. Park, Y. Diao, Chem. Soc. Rev. 2020, 49, 8287-8314.
N. K. Nath, M. K. Panda, S. C. Sahoo, P. Naumov, CrystEngComm 2014, 16, 1850-1858.
S. Saha, M. K. Mishra, C. M. Reddy, G. R. Desiraju, Acc. Chem. Res. 2018, 51, 2957-2967.
K. J. Ramos, D. E. Hooks, D. F. Bahr, Philos. Mag. 2009, 89, 2381-2402.
F. Liu, D. E. Hooks, N. Li, N. A. Mara, J. A. Swift, Chem. Mater. 2018, 30, 3798-3805.
A. El Naggar, M. A. Youssef, AIMS Mater. Sci. 2020, 7, 836-858.
I. A. Olson, A. G. Shtukenberg, B. Kahr, M. D. Ward, Rep. Prog. Phys. 2018, 81, 096501.
A. G. Shtukenberg, S. S. Lee, B. Kahr, M. D. Ward, Annu. Rev. Chem. Biomol. Eng. 2014, 5, 77-96.
N. El-Atab, R. B. Mishra, F. Al-Modaf, L. Joharji, A. A. Alsharif, H. Alamoudi, M. Diaz, N. Qaiser, M. M. Hussain, Adv. Intell. Syst. 2020, 2, 2000128.
J. A. Johnson, K. J. Manke, D. G. Veyssett, A. A. Maznev, K. J. Ramos, D. E. Hooks, K. A. Nelson, J. Appl. Phys. 2011, 110, 113513.
S. Speziale, F. Jiang, C. L. Caylor, S. Kriminski, C.-S. Zha, R. E. Thorne, T. S. Duffy, Biophys. J. 2003, 85, 3202-3213.
D. Rus, M. T. Tolley, Nature 2015, 521, 467-475.
D. Labonte, A. K. Lenz, M. L. Oyen, Acta Biomater. 2017, 57, 373-383.
I. Azuri, E. Meirzadeh, D. Ehre, S. R. Cohen, A. M. Rappe, M. Lahav, I. Lubomirsky, L. Kronik, Angew. Chem. Int. Ed. 2015, 54, 13566-13570;
Angew. Chem. 2015, 127, 13770-13774.
D. P. Karothu, G. Dushaq, E. Ahmed, L. Catalano, S. Polavaram, R. Ferreira, L. Li, S. Mohamed, M. Rasras, P. Naumov, Nat. Commun. 2021, 12, 1326.
K. J. Ramos, D. F. Bahr, J. Mater. Res. 2007, 22, 2037-2045.
R. O. Ritchie, Nat. Mater. 2011, 10, 817-822.
B. R. Lawn, D. B. Marshall, J. Am. Ceram. Soc. 1979, 62, 347-350.
S. Park, J. B. Quinn, E. Romberg, D. Arola, Dent. Mater. 2008, 24, 1477-1485.
Y. Feng, D. J. W. Grant, Pharm. Res. 2006, 23, 1608-1616.
M. Egart, I. Ilic, B. Jankovic, N. Lah, S. Srcic, Int. J. Pharm. 2014, 472, 347-355.
M. Sakai, J. Mater. Res. 1999, 14, 3630-3639.
M. F. Ashby, Materials selection in mechanical design, Butterworth-Heinemann, 2016.
CES Selector Software, Granta Design Limited, Cambridge, UK www.grantadesign.com (accessed: February 2021).
M. J. Turner, S. P. Thomas, M. W. Shi, D. Jayatilaka, M. A. Spackman, Chem. Commun. 2015, 51, 3735-3738.