Studies on the Vitrified and Cryomilled Bosentan.


Journal

Molecular pharmaceutics
ISSN: 1543-8392
Titre abrégé: Mol Pharm
Pays: United States
ID NLM: 101197791

Informations de publication

Date de publication:
03 01 2022
Historique:
pubmed: 2 12 2021
medline: 29 3 2022
entrez: 1 12 2021
Statut: ppublish

Résumé

In this paper, several experimental techniques [X-ray diffraction, differential scanning calorimetry (DSC), thermogravimetry, Fourier transform infrared spectroscopy, and broad-band dielectric spectroscopy] have been applied to characterize the structural and thermal properties, H-bonding pattern, and molecular dynamics of amorphous bosentan (BOS) obtained by vitrification and cryomilling of the monohydrate crystalline form of this drug. Samples prepared by these two methods were found to be similar with regard to their internal structure, H-bonding scheme, and structural (α) dynamics in the supercooled liquid state. However, based on the analysis of α-relaxation times (dielectric measurements) predicted for temperatures below the glass-transition temperature (

Identifiants

pubmed: 34851124
doi: 10.1021/acs.molpharmaceut.1c00613
pmc: PMC8728735
doi:

Substances chimiques

Bosentan Q326023R30

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

80-90

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Auteurs

Aldona Minecka (A)

Department of Pharmacognosy and Phytochemistry, Faculty of Pharmaceutical Sciences in Sosnowiec, Medical University of Silesia in Katowice, ul. Jagiellonska 4, 41-200 Sosnowiec, Poland.

Krzysztof Chmiel (K)

Department of Pharmacognosy and Phytochemistry, Faculty of Pharmaceutical Sciences in Sosnowiec, Medical University of Silesia in Katowice, ul. Jagiellonska 4, 41-200 Sosnowiec, Poland.

Karolina Jurkiewicz (K)

Institute of Physics, Faculty of Science and Technology, University of Silesia in Katowice, 75 Pułku Piechoty 1, 41-500 Chorzów, Poland.

Barbara Hachuła (B)

Institute of Chemistry, University of Silesia in Katowice, 40-006 Katowice, Poland.

Rafał Łunio (R)

Polpharma SA, 83-200 Starogard Gdański, Poland.

Daniel Żakowiecki (D)

Chemische Fabrik Budenheim KG, Rheinstrasse 27, 55257 Budenheim, Germany.

Kinga Hyla (K)

Chair and Department of Pharmaceutical Technology, Faculty of Pharmacy, Poznan University of Medical Sciences, 60-780 Poznan, Poland.

Bartłomiej Milanowski (B)

Chair and Department of Pharmaceutical Technology, Faculty of Pharmacy, Poznan University of Medical Sciences, 60-780 Poznan, Poland.
GENERICA Pharmaceutical Lab, Regionalne Centrum Zdrowia Sp. z o.o., Na Kępie 3, 64-360 Zbąszyń, Poland.

Kajetan Koperwas (K)

Institute of Physics, Faculty of Science and Technology, University of Silesia in Katowice, 75 Pułku Piechoty 1, 41-500 Chorzów, Poland.

Kamil Kamiński (K)

Institute of Physics, Faculty of Science and Technology, University of Silesia in Katowice, 75 Pułku Piechoty 1, 41-500 Chorzów, Poland.

Marian Paluch (M)

Institute of Physics, Faculty of Science and Technology, University of Silesia in Katowice, 75 Pułku Piechoty 1, 41-500 Chorzów, Poland.

Ewa Kamińska (E)

Department of Pharmacognosy and Phytochemistry, Faculty of Pharmaceutical Sciences in Sosnowiec, Medical University of Silesia in Katowice, ul. Jagiellonska 4, 41-200 Sosnowiec, Poland.

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Classifications MeSH