Study of the Viscosity and Thermal Characteristics of Polyolefins/Solvent Mixtures: Applications for Plastic Pyrolysis.


Journal

ACS omega
ISSN: 2470-1343
Titre abrégé: ACS Omega
Pays: United States
ID NLM: 101691658

Informations de publication

Date de publication:
07 Dec 2021
Historique:
received: 01 09 2021
accepted: 10 11 2021
entrez: 13 12 2021
pubmed: 14 12 2021
medline: 14 12 2021
Statut: epublish

Résumé

Plastic pollution is one of the biggest environmental problems that the world is currently facing. Pyrolysis is a frontier technique aimed at converting plastic waste back into virgin-quality resin. However, the transfer of the waste plastic feed into the pyrolysis reactor must be optimized before the process can be upscaled to a continuous process. In this study, a new solvent that reduces the viscosity of molten plastic was introduced and characterized. The results revealed that the polymers are soluble in the ratio of up to 75 wt % plastic and 25 wt % solvent at 240 °C. The viscosity of pure low-density polyethylene (LDPE), high-density polyethylene (HDPE), and polypropylene (PP) in the solvent was measured in different weight percentages of polymer in solvent (30-80 wt %) and at 160, 180, 200, 220, 240, and 260 °C. The viscosity decreased with the decreasing polymer-weight percentage and with increasing temperature. The viscosity of LDPE/solvent and PP

Identifiants

pubmed: 34901633
doi: 10.1021/acsomega.1c04809
pmc: PMC8655911
doi:

Types de publication

Journal Article

Langues

eng

Pagination

32832-32840

Informations de copyright

© 2021 The Authors. Published by American Chemical Society.

Déclaration de conflit d'intérêts

The authors declare no competing financial interest.

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Auteurs

Ali Zolghadr (A)

Department of Chemical Engineering, Michigan Technological University, 1400 Townsend Drive, Houghton, Michigan 49931, United States.

Azarnoosh Foroozandehfar (A)

Department of Chemical Engineering, Michigan Technological University, 1400 Townsend Drive, Houghton, Michigan 49931, United States.

Daniel G Kulas (DG)

Department of Chemical Engineering, Michigan Technological University, 1400 Townsend Drive, Houghton, Michigan 49931, United States.

David Shonnard (D)

Department of Chemical Engineering, Michigan Technological University, 1400 Townsend Drive, Houghton, Michigan 49931, United States.

Classifications MeSH