Characterizing photochemical ageing processes of microplastic materials using multivariate analysis of infrared spectra.

Microplastics in the environment are an emerging concern due to impacts on human and environmental health. In addition to direct effects on biota, microplastics influence the fate and distribution of trace organic contaminants through sorption and transport. Environmental weathering may influence the rate and extent of chemical sorption. Changes in the surface characteristics of four common plastics including low-density polyethylene (LDPE), high-density polyethylene (HDPE), polypropylene (PP), and polystyrene (PS) were followed under the influence of both artificial light (UV-B) and natural sunlight for up to six months. Attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectra were collected at regular intervals. Principal component analysis (PCA) of the full dataset of UV-B weathered samples (