Enantioselective Fluorination of α-Substituted β-Diketones Using β,β-Diaryl Serines.


Journal

Organic letters
ISSN: 1523-7052
Titre abrégé: Org Lett
Pays: United States
ID NLM: 100890393

Informations de publication

Date de publication:
14 01 2022
Historique:
pubmed: 22 12 2021
medline: 22 12 2021
entrez: 21 12 2021
Statut: ppublish

Résumé

We report the enantioselective fluorination of α-substituted β-diketones using β,β-diaryl serines as a primary amine organocatalyst. The reaction affords the corresponding fluorinated products in yields of 74 to 99% with excellent enantioselectivity (75-95%

Identifiants

pubmed: 34931846
doi: 10.1021/acs.orglett.1c04104
doi:

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

420-424

Auteurs

Samira Poorsadeghi (S)

Department of Chemistry, Biology and Marine Science, University of the Ryukyus, Senbaru 1, Nishihara, Nakagami, Okinawa 903-0213, Japan.

Katsuki Endo (K)

Department of Chemistry, Biology and Marine Science, University of the Ryukyus, Senbaru 1, Nishihara, Nakagami, Okinawa 903-0213, Japan.

Satoru Arimitsu (S)

Department of Chemistry, Biology and Marine Science, University of the Ryukyus, Senbaru 1, Nishihara, Nakagami, Okinawa 903-0213, Japan.

Classifications MeSH