A Use of Tritium-Labeled Peat Fulvic Acids and Polyphenolic Derivatives for Designing Pharmacokinetic Experiments on Mice.

fulvic acid intravenous lignin oral pharmacokinetics polyphenolic composition tissue distribution tritium label

Journal

Biomedicines
ISSN: 2227-9059
Titre abrégé: Biomedicines
Pays: Switzerland
ID NLM: 101691304

Informations de publication

Date de publication:
29 Nov 2021
Historique:
received: 31 10 2021
revised: 23 11 2021
accepted: 26 11 2021
entrez: 24 12 2021
pubmed: 25 12 2021
medline: 25 12 2021
Statut: epublish

Résumé

Natural products (e.g., polyphenols) have been used as biologically active compounds for centuries. Still, the mechanisms of biological activity of these multicomponent systems are poorly understood due to a lack of appropriate experimental techniques. The method of tritium thermal bombardment allows for non-selective labeling and tracking of all components of complex natural systems. In this study, we applied it to label two well-characterized polyphenolic compounds, peat fulvic acid (FA-Vi18) and oxidized lignin derivative (BP-Cx-1), of predominantly hydrophilic and hydrophobic character, respectively. The identity of the labeled samples was confirmed using size exclusion chromatography. Using ultra-high resolution Fourier transform ion cyclotron resonance mass spectrometry (FT ICR MS), key differences in the molecular composition of BP-Cx-1 and FA-Vi18 were revealed. The labeled samples ([

Identifiants

pubmed: 34944604
pii: biomedicines9121787
doi: 10.3390/biomedicines9121787
pmc: PMC8698565
pii:
doi:

Types de publication

Journal Article

Langues

eng

Subventions

Organisme : Russian Science Foundation
ID : 20-15-00330; 21-73-20202

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Auteurs

Gennady A Badun (GA)

Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia.

Maria G Chernysheva (MG)

Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia.

Yury V Zhernov (YV)

Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia.
Department of General Hygiene, F. Erismann Institute of Public Health, I.M. Sechenov First Moscow State Medical University (Sechenov University), 119435 Moscow, Russia.

Alina S Poroshina (AS)

National Research Center, Institute of Immunology FMBA of Russia, 115522 Moscow, Russia.

Valery V Smirnov (VV)

Department of General Hygiene, F. Erismann Institute of Public Health, I.M. Sechenov First Moscow State Medical University (Sechenov University), 119435 Moscow, Russia.
National Research Center, Institute of Immunology FMBA of Russia, 115522 Moscow, Russia.

Sergey E Pigarev (SE)

N.N. Petrov National Medical Research Center of Oncology, Ministry of Health of Russian Federation, 197758 Saint Petersburg, Russia.
Nobel Ltd., 192012 Saint Petersburg, Russia.

Tatiana A Mikhnevich (TA)

Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia.

Dmitry S Volkov (DS)

Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia.
V.V. Dokuchaev Soil Science Institute of RAAS, 119017 Moscow, Russia.

Irina V Perminova (IV)

Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia.

Elena I Fedoros (EI)

N.N. Petrov National Medical Research Center of Oncology, Ministry of Health of Russian Federation, 197758 Saint Petersburg, Russia.
Nobel Ltd., 192012 Saint Petersburg, Russia.

Classifications MeSH