Towards developing novel and sustainable molecular light-to-heat converters.


Journal

Chemical science
ISSN: 2041-6520
Titre abrégé: Chem Sci
Pays: England
ID NLM: 101545951

Informations de publication

Date de publication:
01 Dec 2021
Historique:
received: 13 09 2021
accepted: 18 10 2021
entrez: 3 1 2022
pubmed: 4 1 2022
medline: 4 1 2022
Statut: epublish

Résumé

Light-to-heat conversion materials generate great interest due to their widespread applications, notable exemplars being solar energy harvesting and photoprotection. Another more recently identified potential application for such materials is in molecular heaters for agriculture, whose function is to protect crops from extreme cold weather and extend both the growing season and the geographic areas capable of supporting growth, all of which could help reduce food security challenges. To address this demand, a new series of phenolic-based barbituric absorbers of ultraviolet (UV) radiation has been designed and synthesised in a sustainable manner. The photophysics of these molecules has been studied in solution using femtosecond transient electronic and vibrational absorption spectroscopies, allied with computational simulations and their potential toxicity assessed by

Identifiants

pubmed: 34976344
doi: 10.1039/d1sc05077j
pii: d1sc05077j
pmc: PMC8634993
doi:

Types de publication

Journal Article

Langues

eng

Pagination

15239-15252

Informations de copyright

This journal is © The Royal Society of Chemistry.

Déclaration de conflit d'intérêts

There are no conflicts to declare.

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Auteurs

Temitope T Abiola (TT)

Department of Chemistry, University of Warwick Gibbet Hill Road Coventry CV4 7AL UK v.stavros@warwick.ac.uk.

Benjamin Rioux (B)

URD Agro-Biotechnologies (ABI), CEBB, AgroParisTech 51110 Pomacle France florent.allais@agroparistech.fr.

Josene M Toldo (JM)

Aix Marseille Université, CNRS, ICR Marseille France josene-maria.toldo@univ-amu.fr.

Jimmy Alarcan (J)

Department of Food Safety, German Federal Institute for Risk Assessment Max-Dohrn-Str. 8-10 10589 Berlin Germany Albert.Braeuning@bfr.bund.de.

Jack M Woolley (JM)

Department of Chemistry, University of Warwick Gibbet Hill Road Coventry CV4 7AL UK v.stavros@warwick.ac.uk.

Matthew A P Turner (MAP)

Department of Chemistry, University of Warwick Gibbet Hill Road Coventry CV4 7AL UK v.stavros@warwick.ac.uk.
Department of Physics, University of Warwick Gibbet Hill Road Coventry CV4 7AL UK.

Daniel J L Coxon (DJL)

Department of Chemistry, University of Warwick Gibbet Hill Road Coventry CV4 7AL UK v.stavros@warwick.ac.uk.
Department of Physics, University of Warwick Gibbet Hill Road Coventry CV4 7AL UK.
EPSRC Centre for Doctoral Training in Diamond Science and Technology UK.

Mariana Telles do Casal (M)

Aix Marseille Université, CNRS, ICR Marseille France josene-maria.toldo@univ-amu.fr.

Cédric Peyrot (C)

URD Agro-Biotechnologies (ABI), CEBB, AgroParisTech 51110 Pomacle France florent.allais@agroparistech.fr.

Matthieu M Mention (MM)

URD Agro-Biotechnologies (ABI), CEBB, AgroParisTech 51110 Pomacle France florent.allais@agroparistech.fr.

Wybren J Buma (WJ)

Van 't Hoff Institute for Molecular Sciences, University of Amsterdam Amsterdam The Netherlands.
Institute for Molecules and Materials, FELIX Laboratory, Radboud University 6525 ED Nijmegen The Netherlands.

Michael N R Ashfold (MNR)

School of Chemistry, University of Bristol Cantock's Close Bristol BS8 1TS UK.

Albert Braeuning (A)

Department of Food Safety, German Federal Institute for Risk Assessment Max-Dohrn-Str. 8-10 10589 Berlin Germany Albert.Braeuning@bfr.bund.de.

Mario Barbatti (M)

Aix Marseille Université, CNRS, ICR Marseille France josene-maria.toldo@univ-amu.fr.
Institut Universitaire de France 75231 Paris France.

Vasilios G Stavros (VG)

Department of Chemistry, University of Warwick Gibbet Hill Road Coventry CV4 7AL UK v.stavros@warwick.ac.uk.

Florent Allais (F)

URD Agro-Biotechnologies (ABI), CEBB, AgroParisTech 51110 Pomacle France florent.allais@agroparistech.fr.

Classifications MeSH