Tunable induced circular dichroism in gels.
chiral gels
chirality transfer
induced optical activity
optically active dyes
wavelength tunability
Journal
Chirality
ISSN: 1520-636X
Titre abrégé: Chirality
Pays: United States
ID NLM: 8914261
Informations de publication
Date de publication:
03 2022
03 2022
Historique:
revised:
13
12
2021
received:
09
07
2021
accepted:
14
12
2021
pubmed:
7
1
2022
medline:
19
2
2022
entrez:
6
1
2022
Statut:
ppublish
Résumé
The ICD phenomenon has drawn a lot of attention in recent years in applicable fields such as chiral sensing and chiroptical devices. In this work, we first gaze at the issues of thin spin-coated films not being able to deliver consistent ICD signals. A hypothesis of the underlying problem is proposed through a brief elucidation of the spin-coating process. To confirm and eliminate the uncontrollable dynamic factors with spin coating, we then dedicate our efforts to develop a new gel system based on chiral L-/D-N',N'-Dibenzoyl-cystine. Achiral dye molecules are intercalated in a DBC gel through a "one-step" preparation procedure. Compared to the former spin-coating system, significantly improved reproducibility of the new gel system is demonstrated. Besides, the ICD signals can be customized in a broad spectral range (wavelength tunability) by substituting dye molecules. Finally, we discuss the potential applications of this interesting system.
Substances chimiques
Gels
0
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM
Pagination
550-558Subventions
Organisme : Deutsche Forschungsgemeinschaft
ID : HE 3454/21-2
Informations de copyright
© 2022 The Authors. Chirality published by Wiley Periodicals LLC.
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