Ir(IV) Sulfoxide-Pincer Complexes by Three-Electron Oxidative Additions of Br
Journal
Inorganic chemistry
ISSN: 1520-510X
Titre abrégé: Inorg Chem
Pays: United States
ID NLM: 0366543
Informations de publication
Date de publication:
24 Jan 2022
24 Jan 2022
Historique:
pubmed:
7
1
2022
medline:
7
1
2022
entrez:
6
1
2022
Statut:
ppublish
Résumé
Oxidative addition of 1.5 equiv of bromine or iodine to a Ir(I) sulfoxide pincer complex affords the corresponding Ir(IV) tris-bromido or tris-iodido complexes, respectively. The unprecedented trap-free reductive elimination of iodine from the Ir(IV)-iodido complex is induced by coordination of ligands or donor solvents. In the case of added I
Identifiants
pubmed: 34990121
doi: 10.1021/acs.inorgchem.1c02956
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM