Spatial and temporal variability and sources of dissolved trace elements in the Sava River (Slovenia, Croatia).
Anthropogenic impact
Concentration–discharge relationship
Dissolved elements
Source contributions
The Sava River
Journal
Environmental science and pollution research international
ISSN: 1614-7499
Titre abrégé: Environ Sci Pollut Res Int
Pays: Germany
ID NLM: 9441769
Informations de publication
Date de publication:
May 2022
May 2022
Historique:
received:
04
09
2021
accepted:
22
11
2021
pubmed:
12
1
2022
medline:
4
5
2022
entrez:
11
1
2022
Statut:
ppublish
Résumé
The spatial and temporal variability of dissolved trace elements (Al, As, Ba, Cd, Co, Cr, Cu, Fe, Li, Mn, Mo, Ni, Pb, Sb, Sr, Ti, U, V and Zn) in the upper and middle reaches of the Sava River during two campaigns (2007/2008 and 2017/2018) was examined. The study also included important tributaries and wastewater effluents. No crucial change in metal concentrations in the Sava River water between the two sampling periods was detected. Elements Co, Cr, Cu, Fe, Sb and Zn had higher concentrations at several sites in the first period, whereas Ba, Cd and Pb in the second period. The influence of wastewater discharges proved to be negligible. The highest levels of potentially toxic metals (Cd, Cr, Cu, Sb, V and Zn) were found downstream of the industrial town of Sisak. Concentration-discharge relationship of dissolved elements showed a chemostatic behaviour for As, Cr, Cu, Sr and V and chemodynamic behaviour for all other elements. The UNMIX model, used to identify and quantify metal sources, indicated that soil weathering was the main source of most elements (Al, As, Ba, Co, Cu, Fe, Li, Ni, Sb, Sr and V), with an anthropogenic contribution for Cd, Mo, Pb, Ti and Zn, while Mn and U were associated with colloid formation. The Sava River was defined as moderately polluted regarding metals, whose water quality meets environmental quality standards (EQS). These results may help to better understand the behaviour of dissolved metals in rivers under anthropogenic pressure and to control pollution in the Sava River Basin.
Identifiants
pubmed: 35013963
doi: 10.1007/s11356-021-17769-9
pii: 10.1007/s11356-021-17769-9
doi:
Substances chimiques
Metals, Heavy
0
Trace Elements
0
Waste Water
0
Water Pollutants, Chemical
0
Cadmium
00BH33GNGH
Lead
2P299V784P
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
31734-31748Subventions
Organisme : North Atlantic Treaty Organization
ID : 982590
Organisme : Hrvatska Zaklada za Znanost
ID : 7555
Organisme : Hrvatska Zaklada za Znanost
ID : 7031
Informations de copyright
© 2021. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.
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