Heteroleptic Rare-Earth Tris(metallocenes) Containing a Dibenzocyclooctatetraene Dianion.


Journal

Inorganic chemistry
ISSN: 1520-510X
Titre abrégé: Inorg Chem
Pays: United States
ID NLM: 0366543

Informations de publication

Date de publication:
07 Feb 2022
Historique:
pubmed: 20 1 2022
medline: 20 1 2022
entrez: 19 1 2022
Statut: ppublish

Résumé

Isolable heteroleptic tris(metallocenes) containing five-membered and larger rings remain extremely scarce. The utilization of tripositive rare-earth-metal ions with ionic radii >1 Å allowed access to unprecedented and sterically congested dibenzocyclooctatetraenyl (dbCOT) metallocenes, [K(crypt-222)][Cp

Identifiants

pubmed: 35042339
doi: 10.1021/acs.inorgchem.1c03230
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

2444-2454

Auteurs

Elizabeth R Pugliese (ER)

Department of Chemistry, Michigan State University, 578 South Shaw Lane, East Lansing, Michigan 48823, United States.

Florian Benner (F)

Department of Chemistry, Michigan State University, 578 South Shaw Lane, East Lansing, Michigan 48823, United States.

Ernesto Castellanos (E)

Department of Chemistry, Michigan State University, 578 South Shaw Lane, East Lansing, Michigan 48823, United States.

Francis Delano (F)

Department of Chemistry, Michigan State University, 578 South Shaw Lane, East Lansing, Michigan 48823, United States.

Selvan Demir (S)

Department of Chemistry, Michigan State University, 578 South Shaw Lane, East Lansing, Michigan 48823, United States.

Classifications MeSH