Self-Assembly Dynamics of Reconfigurable Colloidal Molecules.

colloidal clusters controlled valence mobile DNA linkers self-assembly structural flexibility

Journal

ACS nano
ISSN: 1936-086X
Titre abrégé: ACS Nano
Pays: United States
ID NLM: 101313589

Informations de publication

Date de publication:
22 02 2022
Historique:
pubmed: 27 1 2022
medline: 16 3 2022
entrez: 26 1 2022
Statut: ppublish

Résumé

Colloidal molecules are designed to mimic their molecular analogues through their anisotropic shape and interactions. However, current experimental realizations are missing the structural flexibility present in real molecules thereby restricting their use as model systems. We overcome this limitation by assembling reconfigurable colloidal molecules from silica particles functionalized with mobile DNA linkers in high yields. We achieve this by steering the self-assembly pathway toward the formation of finite-sized clusters by employing high number ratios of particles functionalized with complementary DNA strands. The size ratio of the two species of particles provides control over the overall cluster size,

Identifiants

pubmed: 35080387
doi: 10.1021/acsnano.1c09088
pmc: PMC8867909
doi:

Substances chimiques

Colloids 0

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

2471-2480

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Auteurs

Indrani Chakraborty (I)

Soft Matter Physics, Huygens-Kamerlingh Onnes Laboratory, Leiden Institute of Physics, PO Box 9504, 2300 RA Leiden, The Netherlands.
Department of Physics, Birla Institute of Technology and Science, Pilani - K K Birla Goa Campus, Zuarinagar, Goa 403726, India.

Daniel J G Pearce (DJG)

Institute-Lorentz, Universiteit Leiden, PO Box 9506, 2300 RA Leiden, The Netherlands.
Department of Mathematics, Massachusetts Institute of Technology, 182 Memorial Drive, Cambridge, Massachusetts 02142, United States.
Department of Theoretical Physics, University of Geneva, Quai Ernest Ansermet 30, 1205 Geneva, Switzerland.

Ruben W Verweij (RW)

Soft Matter Physics, Huygens-Kamerlingh Onnes Laboratory, Leiden Institute of Physics, PO Box 9504, 2300 RA Leiden, The Netherlands.

Sabine C Matysik (SC)

Soft Matter Physics, Huygens-Kamerlingh Onnes Laboratory, Leiden Institute of Physics, PO Box 9504, 2300 RA Leiden, The Netherlands.
Yusuf Hamied Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, United Kingdom.

Luca Giomi (L)

Institute-Lorentz, Universiteit Leiden, PO Box 9506, 2300 RA Leiden, The Netherlands.

Daniela J Kraft (DJ)

Soft Matter Physics, Huygens-Kamerlingh Onnes Laboratory, Leiden Institute of Physics, PO Box 9504, 2300 RA Leiden, The Netherlands.

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