Deciphering the Role of Noncovalent Interactions in the Conformations of Dibenzo-1,5-dichalcogenocines.

chalcogen bond conformational analysis noncovalent interaction tellurium σ-hole

Journal

ChemPlusChem
ISSN: 2192-6506
Titre abrégé: Chempluschem
Pays: Germany
ID NLM: 101580948

Informations de publication

Date de publication:
04 2022
Historique:
revised: 03 01 2022
received: 24 11 2021
pubmed: 2 2 2022
medline: 6 4 2022
entrez: 1 2 2022
Statut: ppublish

Résumé

This work reports a combined experimental and theoretical study on the new dibenzo-1,5-ditellurocine 2-Te in order to get an overview on the parameters controlling conformational change and to explain the differences with sulfur and selenium analogues. The preference of the boat conformer over the chair one is revealed by DFT calculations. For 2-Te, a ΔG value of about 3 kJ/mol was calculated, close to the value measured by NMR (5 kJ/mol). However, DFT calculations with implicit solvation effects could not clearly establish the presence of an intramolecular Te…HC noncovalent interaction (NCI), as observed in the solid state. The Independent Gradient Model (IGM) methodology discloses an existent but probably not sufficiently discriminating Te…HC NCI. It also confirms that van der Waals interactions between phenyl rings is a source of stabilization of the boat conformer. Furthermore, electrostatic potential analysis suggests that chalcogen bonds between Te σ-holes and solvent might play an important role.

Identifiants

pubmed: 35103424
doi: 10.1002/cplu.202100518
doi:

Substances chimiques

Solvents 0
Selenium H6241UJ22B

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202100518

Informations de copyright

© 2022 Wiley-VCH GmbH.

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Auteurs

Robin Weiss (R)

Institute of Chemistry of Strasbourg, UMR 7177 - LASYROC, CNRS and Strasbourg University, 4 rue Blaise Pascal, 67000, Strasbourg, France.

Yann Cornaton (Y)

Institute of Chemistry of Strasbourg, UMR 7177 - LCSOM, CNRS and Strasbourg University, 4 rue Blaise Pascal, 67000, Strasbourg, France.

Hassan Khartabil (H)

CNRS, ICMR UMR 7312, Université de Reims Champagne Ardenne, 51097, Reims, France.

Loïc Groslambert (L)

Institute of Chemistry of Strasbourg, UMR 7177 - LASYROC, CNRS and Strasbourg University, 4 rue Blaise Pascal, 67000, Strasbourg, France.
Institute of Chemistry of Strasbourg, UMR 7177 - LCSOM, CNRS and Strasbourg University, 4 rue Blaise Pascal, 67000, Strasbourg, France.

Eric Hénon (E)

CNRS, ICMR UMR 7312, Université de Reims Champagne Ardenne, 51097, Reims, France.

Patrick Pale (P)

Institute of Chemistry of Strasbourg, UMR 7177 - LASYROC, CNRS and Strasbourg University, 4 rue Blaise Pascal, 67000, Strasbourg, France.

Jean-Pierre Djukic (JP)

Institute of Chemistry of Strasbourg, UMR 7177 - LCSOM, CNRS and Strasbourg University, 4 rue Blaise Pascal, 67000, Strasbourg, France.

Victor Mamane (V)

Institute of Chemistry of Strasbourg, UMR 7177 - LASYROC, CNRS and Strasbourg University, 4 rue Blaise Pascal, 67000, Strasbourg, France.

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