Interactions between conducting surfaces in salt solutions.


Journal

Soft matter
ISSN: 1744-6848
Titre abrégé: Soft Matter
Pays: England
ID NLM: 101295070

Informations de publication

Date de publication:
23 Feb 2022
Historique:
pubmed: 5 2 2022
medline: 5 2 2022
entrez: 4 2 2022
Statut: epublish

Résumé

In this work, we simulate interactions between two perfectly conducting surfaces, immersed in a salt solution. We demonstrate that these forces are quantitatively different from those between (equally charged) non-conducting surfaces. There is, for instance, a significant repulsion between net neutral surfaces. On the other hand, there are also qualitative similarities, with behaviours found with non-conducting surfaces. For instance, there is a non-monotonic dependence of the free energy barrier height, on the salt concentration, and the minimum essentially coincides with a flat profile of the apparent surface charge density (

Identifiants

pubmed: 35118484
doi: 10.1039/d1sm01520f
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

1636-1643

Auteurs

Samuel Stenberg (S)

Theoretical Chemistry, Lund University, P. O. Box 124, 221 00 Lund, Sweden. samuel.stenberg@teokem.lu.se.

Clifford E Woodward (CE)

University College, University of New South Wales (ADFA), Canberra ACT 2600, Australia. c.woodward@adfa.edu.au.

Jan Forsman (J)

Theoretical Chemistry, Lund University, P. O. Box 124, 221 00 Lund, Sweden. samuel.stenberg@teokem.lu.se.

Classifications MeSH