Time-resolved infrared absorption spectroscopy applied to photoinduced reactions: how and why.


Journal

Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology
ISSN: 1474-9092
Titre abrégé: Photochem Photobiol Sci
Pays: England
ID NLM: 101124451

Informations de publication

Date de publication:
Apr 2022
Historique:
received: 30 10 2021
accepted: 28 01 2022
pubmed: 22 2 2022
medline: 6 5 2022
entrez: 21 2 2022
Statut: ppublish

Résumé

Time-resolved infrared (IR) spectroscopy is a widely used technique in the investigation of photoinduced reactions, given its capabilities of providing structural information about the presence of intermediates and the reaction mechanism. Despite the fact that it is used in several fields since the '80s, the communication between the different scientific communities (photochemists, photobiologists, etc.) has been to date quite limited. In some cases, this lack of communication happened-and still happens-even inside the same scientific community (for instance between specialists in ultrafast ps/fs IR and those in "fast" ns/µs/ms IR). Even more surprising is the difficulty of non-specialists to understand the potential of time-resolved IR spectroscopy, despite the fact that IR spectroscopy is normally taught to all chemistry and material science students, and to several biology and physics students. This tutorial review aims at helping to solve these issues, first by providing a comprehensive but reader-friendly overview of the different techniques, and second, by focusing on five "case studies" (from photobiology, gas-phase photocatalysis, photochemistry, semiconductors and metal-carbonyl complexes). We are confident that this approach can help the reader-whichever is its background-to understand the capabilities of time-resolved IR spectroscopy to study the mechanism of photoinduced reactions.

Identifiants

pubmed: 35188651
doi: 10.1007/s43630-022-00180-9
pii: 10.1007/s43630-022-00180-9
doi:

Substances chimiques

Coordination Complexes 0

Types de publication

Journal Article Review

Langues

eng

Sous-ensembles de citation

IM

Pagination

557-584

Commentaires et corrections

Type : ErratumIn

Informations de copyright

© 2022. The Author(s), under exclusive licence to European Photochemistry Association, European Society for Photobiology.

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Auteurs

Alberto Mezzetti (A)

Laboratoire de Réactivité de Surface (LRS), UMR 7197, Sorbonne Université, Campus Pierre et Marie Curie, 4 Pl Jussieu, 75005, Paris, France. alberto.mezzetti@sorbonne-universite.fr.

Josefine Schnee (J)

Laboratoire de Réactivité de Surface (LRS), UMR 7197, Sorbonne Université, Campus Pierre et Marie Curie, 4 Pl Jussieu, 75005, Paris, France.

Andrea Lapini (A)

European Laboratory for Non Linear Spectroscopy (LENS), via N. Carrara 1, 50019, Sesto Fiorentino, Italy.
Dipartimento di Scienze Chimiche della Vita e della Sostenibilità Ambientale, Parco Area delle Scienze 17/A, 43124, Parma, Italy.

Mariangela Di Donato (M)

European Laboratory for Non Linear Spectroscopy (LENS), via N. Carrara 1, 50019, Sesto Fiorentino, Italy. didonato@lens.unifi.it.
ICCOM-CNR via Madonna del Piano 10, 50019, Sesto Fiorentino, Italy. didonato@lens.unifi.it.

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