New paradigm for configurational entropy in glass-forming systems.


Journal

Scientific reports
ISSN: 2045-2322
Titre abrégé: Sci Rep
Pays: England
ID NLM: 101563288

Informations de publication

Date de publication:
23 Feb 2022
Historique:
received: 23 08 2021
accepted: 19 01 2022
entrez: 24 2 2022
pubmed: 25 2 2022
medline: 25 2 2022
Statut: epublish

Résumé

We show that on cooling towards glass transition configurational entropy exhibits more significant changes than predicted by classic relation. A universal formula according to Kauzmann temperature [Formula: see text] is given: [Formula: see text], where [Formula: see text]. The exponent [Formula: see text] is hypothetically linked to dominated local symmetry. Such a behaviour is coupled to previtreous evolution of heat capacity [Formula: see text] associated with finite temperature singularity. These lead to generalised VFT relation, for which the basic equation is retrieved. For many glass-formers, basic VFT equation may have only an effective meaning. A universal-like reliability of the Stickel operator analysis for detecting dynamic crossover phenomenon is also questioned. Notably, distortions-sensitive and derivative-based analysis focused on previtreous changes of configurational entropy and heat capacity for glycerol, ethanol and liquid crystal is applied.

Identifiants

pubmed: 35197481
doi: 10.1038/s41598-022-05897-2
pii: 10.1038/s41598-022-05897-2
pmc: PMC8866542
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

3058

Subventions

Organisme : Narodowe Centrum Nauki
ID : 2016/21/B/ST3/02203
Organisme : Narodowe Centrum Nauki
ID : 2017/25/B/ST3/02458
Organisme : Narodowe Centrum Nauki
ID : 2019/32/T/ST3/00621

Informations de copyright

© 2022. The Author(s).

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Auteurs

Aleksandra Drozd-Rzoska (A)

Institute of High Pressure Physics of the Polish Academy of Sciences, Warsaw, Poland.

Sylwester J Rzoska (SJ)

Institute of High Pressure Physics of the Polish Academy of Sciences, Warsaw, Poland.

Szymon Starzonek (S)

Institute of High Pressure Physics of the Polish Academy of Sciences, Warsaw, Poland. starzoneks@unipress.waw.pl.

Classifications MeSH