New paradigm for configurational entropy in glass-forming systems.
Journal
Scientific reports
ISSN: 2045-2322
Titre abrégé: Sci Rep
Pays: England
ID NLM: 101563288
Informations de publication
Date de publication:
23 Feb 2022
23 Feb 2022
Historique:
received:
23
08
2021
accepted:
19
01
2022
entrez:
24
2
2022
pubmed:
25
2
2022
medline:
25
2
2022
Statut:
epublish
Résumé
We show that on cooling towards glass transition configurational entropy exhibits more significant changes than predicted by classic relation. A universal formula according to Kauzmann temperature [Formula: see text] is given: [Formula: see text], where [Formula: see text]. The exponent [Formula: see text] is hypothetically linked to dominated local symmetry. Such a behaviour is coupled to previtreous evolution of heat capacity [Formula: see text] associated with finite temperature singularity. These lead to generalised VFT relation, for which the basic equation is retrieved. For many glass-formers, basic VFT equation may have only an effective meaning. A universal-like reliability of the Stickel operator analysis for detecting dynamic crossover phenomenon is also questioned. Notably, distortions-sensitive and derivative-based analysis focused on previtreous changes of configurational entropy and heat capacity for glycerol, ethanol and liquid crystal is applied.
Identifiants
pubmed: 35197481
doi: 10.1038/s41598-022-05897-2
pii: 10.1038/s41598-022-05897-2
pmc: PMC8866542
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
3058Subventions
Organisme : Narodowe Centrum Nauki
ID : 2016/21/B/ST3/02203
Organisme : Narodowe Centrum Nauki
ID : 2017/25/B/ST3/02458
Organisme : Narodowe Centrum Nauki
ID : 2019/32/T/ST3/00621
Informations de copyright
© 2022. The Author(s).
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