A Fully Conjugated Porphyrin-[36]Octaphyrin-Porphyrin Hybrid Tape Exhibiting Möbius Aromaticity.

Möbius aromaticity NIR absorption expanded porphyrin porphyrin tape transannular bond formation

Journal

Chemistry (Weinheim an der Bergstrasse, Germany)

ISSN: 1521-3765

Titre abrégé: Chemistry

Pays: Germany

ID NLM: 9513783

Informations de publication

Date de publication:
06 Apr 2022

Historique:

received: 02 02 2022

pubmed: 27 2 2022

medline: 27 2 2022

entrez: 26 2 2022

Statut: ppublish

Résumé

Directly meso-meso linked porphyrin-tetrabromo[36]octaphyrin-porphyrin hybrid trimer 10 was successfully synthesized via acid-catalyzed condensation reaction and subsequent oxidation. Zn

Identifiants

DOI: 10.1002/chem.202200328 PMID: 35218265

pubmed: 35218265

doi: 10.1002/chem.202200328

doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

Pagination

e202200328

Subventions

Organisme : Japan Society for the Promotion of Science

ID : JP20K05463 and JP21H05480

Informations de copyright

Références

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Deposition Number 2145565 (11) contains the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe http://www.ccdc.cam.ac.uk/structures Access Structures service.

Deposition Number 2145566 (12) contains the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe http://www.ccdc.cam.ac.uk/structures Access Structures service.

Such shifts were also observed for porphyrin-hexaphyrin hybrid trimers and tapes. See Ref. [4].

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DFT calculations were performed at the level, B3LYP/6-31G (d) for C, H, N, F, Br and LANL2DZ for Ni, Zn, using the Gaussian 16 program. See the Supporting Information for full citation.

A similar red-shift was observed in the case of porphyrin tapes: T. Ikeue, N. Aratani, A. Osuka, Isr. J. Chem. 2005, 45, 293.