Organocatalytic asymmetric nitroso aldol reaction of α
N-selectivity
Takemoto catalyst
enantioselective
malonamate
nitroso aldol reaction
Journal
Beilstein journal of organic chemistry
ISSN: 1860-5397
Titre abrégé: Beilstein J Org Chem
Pays: Germany
ID NLM: 101250746
Informations de publication
Date de publication:
2022
2022
Historique:
received:
12
11
2021
accepted:
11
02
2022
entrez:
14
3
2022
pubmed:
15
3
2022
medline:
15
3
2022
Statut:
epublish
Résumé
A practical enantioselective N-selective nitroso aldol reaction of α-methylmalonamates with a nitrosoarene is reported. The reaction employs the Takemoto thiourea catalyst for the induction of enantioselectivity, and the corresponding optically active oxyaminated malonamates were obtained in reasonably good yields.
Identifiants
pubmed: 35280951
doi: 10.3762/bjoc.18.25
pmc: PMC8895028
doi:
Types de publication
Journal Article
Langues
eng
Pagination
217-224Informations de copyright
Copyright © 2022, Gupta et al.
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