Efficient Electrochemical Nitrate Reduction to Ammonia with Copper-Supported Rhodium Cluster and Single-Atom Catalysts.

Ammonia Synthesis Copper Nanowires Electrochemical Nitrate Reduction Hydrogen Transfer Mechanism Single-Atom Catalysts

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
07 Jun 2022
Historique:
received: 16 02 2022
pubmed: 18 3 2022
medline: 18 3 2022
entrez: 17 3 2022
Statut: ppublish

Résumé

The electrochemical nitrate reduction reaction (NITRR) provides a promising solution for restoring the imbalance in the global nitrogen cycle while enabling a sustainable and decentralized route to source ammonia. Here, we demonstrate a novel electrocatalyst for NITRR consisting of Rh clusters and single-atoms dispersed onto Cu nanowires (NWs), which delivers a partial current density of 162 mA cm

Identifiants

pubmed: 35297151
doi: 10.1002/anie.202202556
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202202556

Subventions

Organisme : the Chinese Thousand Talents Program for Young Professionals
Organisme : the startup funding from Nankai University
Organisme : the "111" project
ID : B16027
Organisme : the Spanish Ministry of Science & Innovation for the "Ramon y Cajal" Program
ID : RYC- RYC2018-023888-I
Organisme : the Singapore Ministry of Education AcRF Tier 2
ID : 2016-T2-2-153, 2016-T2-1-131
Organisme : AcRF Tier 1
ID : RG7/18 and RG161/19
Organisme : the Early Postdoc Mobility Fellowship
ID : P2ELP2_199800

Informations de copyright

© 2022 Wiley-VCH GmbH.

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Auteurs

Huimin Liu (H)

Institute of Photoelectronic Thin Film Devices and Technology, Solar Energy Research Center, Key Laboratory of Photoelectronic Thin Film Devices and Technology of Tianjin, Ministry of Education Engineering Research Center of Thin Film Photoelectronic Technology, Renewable Energy Conversion and Storage Center, Nankai University, Tianjin, 300350, China.

Xiuyao Lang (X)

Institute of Photoelectronic Thin Film Devices and Technology, Solar Energy Research Center, Key Laboratory of Photoelectronic Thin Film Devices and Technology of Tianjin, Ministry of Education Engineering Research Center of Thin Film Photoelectronic Technology, Renewable Energy Conversion and Storage Center, Nankai University, Tianjin, 300350, China.

Chao Zhu (C)

School of Materials Science and Engineering, Nanyang Technological University, Singapore, 639798, Singapore.

Janis Timoshenko (J)

Department of Interface Science, Fritz-Haber-Institut der Max-Planck-Gesellschaft, 14195, Berlin, Germany.

Martina Rüscher (M)

Department of Interface Science, Fritz-Haber-Institut der Max-Planck-Gesellschaft, 14195, Berlin, Germany.

Lichen Bai (L)

Department of Interface Science, Fritz-Haber-Institut der Max-Planck-Gesellschaft, 14195, Berlin, Germany.

Néstor Guijarro (N)

Institute of Electrochemistry, University of Alicante, 03080, Alicante, Spain.

Haibo Yin (H)

State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing, 100084, China.

Yue Peng (Y)

State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing, 100084, China.

Junhua Li (J)

State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing, 100084, China.

Zheng Liu (Z)

School of Materials Science and Engineering, Nanyang Technological University, Singapore, 639798, Singapore.

Weichao Wang (W)

Institute of Photoelectronic Thin Film Devices and Technology, Solar Energy Research Center, Key Laboratory of Photoelectronic Thin Film Devices and Technology of Tianjin, Ministry of Education Engineering Research Center of Thin Film Photoelectronic Technology, Renewable Energy Conversion and Storage Center, Nankai University, Tianjin, 300350, China.

Beatriz Roldan Cuenya (BR)

Department of Interface Science, Fritz-Haber-Institut der Max-Planck-Gesellschaft, 14195, Berlin, Germany.

Jingshan Luo (J)

Institute of Photoelectronic Thin Film Devices and Technology, Solar Energy Research Center, Key Laboratory of Photoelectronic Thin Film Devices and Technology of Tianjin, Ministry of Education Engineering Research Center of Thin Film Photoelectronic Technology, Renewable Energy Conversion and Storage Center, Nankai University, Tianjin, 300350, China.

Classifications MeSH