BSSE-corrected consistent Gaussian basis sets of triple-zeta valence with polarization quality of the fifth period for solid-state calculations.

5th period CRYSTAL basis sets pob-TZVP-rev2 solid-state calculations

Journal

Journal of computational chemistry
ISSN: 1096-987X
Titre abrégé: J Comput Chem
Pays: United States
ID NLM: 9878362

Informations de publication

Date de publication:
05 05 2022
Historique:
revised: 03 03 2022
received: 13 01 2022
accepted: 04 03 2022
pubmed: 19 3 2022
medline: 19 3 2022
entrez: 18 3 2022
Statut: ppublish

Résumé

Revised versions of our published pob-TZVP basis sets [Laun, J.; Vilela Oliveira, D. and Bredow, T., J. Comput. Chem., 2018, 39 (19), 1285-1290] have been derived for periodic quantum-chemical solid-state calculations. They complete our pob-TZVP-rev2 series [Vilela Oliveira, D.; Laun, J.; Peintinger, M. F. and Bredow, T., J. Comput. Chem., 2019, 40 (27), 2364-2376 and Laun, J. and Bredow, J. Comput. Chem. 2021; 42 (15), 1064-1072] for the elements of the fifth period and are based on the fully relativistic effective core potentials (ECPs) of the Stuttgart/Cologne group and the def2-TZVP valence basis of the Ahlrichs group. The pob-TZVP-rev2 basis sets are developed to minimize the basis set superposition error (BSSE) in crystalline systems. For the applied PW1PW hybrid functional, the overall performance, transferability, and SCF stability of the resulting pob-TZVP-rev2 basis sets are significantly improved compared to the original pob-TZVP basis sets. After augmentation with single diffuse s- and p-functions, reference plane-wave band structures of metals can be accurately reproduced.

Identifiants

pubmed: 35302265
doi: 10.1002/jcc.26839
doi:

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

839-846

Informations de copyright

© 2022 The Authors. Journal of Computational Chemistry published by Wiley Periodicals LLC.

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Auteurs

Joachim Laun (J)

Mulliken Center for Theoretical Chemistry, Institut für Physikalische und Theoretische Chemie, University of Bonn, Bonn, Germany.

Thomas Bredow (T)

Mulliken Center for Theoretical Chemistry, Institut für Physikalische und Theoretische Chemie, University of Bonn, Bonn, Germany.

Classifications MeSH