Magnetic Interplay between π-Electrons of Open-Shell Porphyrins and d-Electrons of Their Central Transition Metal Ions.
density functional theory calculations
molecular magnetism
on-surface synthesis
organic open-shell compounds
porphyrins
Journal
Advanced science (Weinheim, Baden-Wurttemberg, Germany)
ISSN: 2198-3844
Titre abrégé: Adv Sci (Weinh)
Pays: Germany
ID NLM: 101664569
Informations de publication
Date de publication:
Jul 2022
Jul 2022
Historique:
revised:
09
02
2022
received:
20
12
2021
pubmed:
19
3
2022
medline:
19
3
2022
entrez:
18
3
2022
Statut:
ppublish
Résumé
Magnetism is typically associated with d- or f-block elements, but can also appear in organic molecules with unpaired π-electrons. This has considerably boosted the interest in such organic materials with large potential for spintronics and quantum applications. While several materials showing either d/f or π-electron magnetism have been synthesized, the combination of both features within the same structure has only scarcely been reported. Open-shell porphyrins (Pors) incorporating d-block transition metal ions represent an ideal platform for the realization of such architectures. Herein, the preparation of a series of open-shell, π-extended Pors that contain magnetically active metal ions (i.e., Cu
Identifiants
pubmed: 35302718
doi: 10.1002/advs.202105906
pmc: PMC9259720
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2105906Subventions
Organisme : European Union's Horizon 2020 research and innovation programme
ID : 785219
Organisme : European Union's Horizon 2020 research and innovation programme
ID : 766864
Organisme : National Natural Science Foundation of China
ID : 22072086
Organisme : Spanish State Research Agency
ID : RTI2018-097895-B-C44
Organisme : MINECO
ID : CTQ2017-85393-P
Organisme : MINECO
ID : PID2020-116490GBI00
Organisme : IMDEA Nanociencia
ID : SEV-2016-0686
Organisme : Swiss National Science Foundation
ID : 200020_182015
Pays : Switzerland
Informations de copyright
© 2022 The Authors. Advanced Science published by Wiley-VCH GmbH.
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